We have investigated the structure and magnetism of self-assembled, 20 nm diameter iron oxide nanoparticles covered by an oleic acid shell for scrutinizing their structural and magnetic correlations. The nanoparticles were spin-coated on an Si substrate as a single monolayer and as a stack of 5 ML forming a multilayer. X-ray scattering (reflectivity and grazing incidence small-angle scattering) confirms high in-plane hexagonal correlation and a good layering property of the nanoparticles. Using polarized neutron reflectivity we have also determined the long range magnetic correlations parallel and perpendicular to the layers in addition to the structural ones. In a field of 5 kOe we determine a magnetization value of about 80% of the saturation value. At remanence the global magnetization is close to zero. However, polarized neutron reflectivity reveals the existence of regions in which magnetic moments of nanoparticles are well aligned, while losing order over longer distances. These findings confirm that in the nanoparticle assembly the magnetic dipole-dipole interaction is rather strong, dominating the collective magnetic properties at room temperature.

We have investigated the magnetic properties of Fe 1−x Ni x -alloys for 13 different compositions ranging from pure Fe to pure Ni. The alloy series was prepared as thin films by co-deposition of Fe and Ni via ultra-high vacuum magnetron sputtering and the concentrations were determined by energy dispersive x-ray fluorescence analysis (EDX). The averaged magnetization and magnetic moment were measured at room temperature using a superconducting quantum interference device (SQUID) magnetometer and a vibrating sample magnetometer (VSM). Making use of x-ray magnetic circular dichroism (XMCD), the individual magnetic moments of Fe and Ni across the alloy concentration range were analyzed; thus their spin and orbital contributions were extracted. The weighted sum of the individual moments agrees very well with the average moments determined via SQUID and VSM. The Ni moment steadily increases from the pure Ni towards to the pure Fe range, while the Fe moment scatters around a value of about 2.4 μ B . Close to the invar composition of x = 0.35 we do not observe an anomaly of the magnetic moments, either of the individual moments or of the average moment. We also discuss different assumptions for the analysis of the XMCD spectra and assess the results in the light of recent theoretical predictions and literature values.

We have studied the magnetic interaction of circular magnetic islands with a dipole character on a square lattice. The square pattern consists of lithographically prepared polycrystalline PdFe islands, 150 nm in diameter and a periodicity of 300 nm. Below the Curie temperature at 260 K, the islands are in a single domain state with isotropic in-plane magnetization. Below 160 K, there is an onset of interisland interaction that leads to a change of the shape of the hysteresis, an increase of coercivity, and a development of in-plane anisotropy. Photoemission electron microscopy with circularly polarized incident x rays tuned to the L3 edge of Fe confirms the increasing correlation of the magnetic islands and the formation of elongated chains, as predicted by Vedmedenko et al. [Phys. Rev. Lett. 95, 207202 (2005)] for contributions from pole interactions of higher order than the dipolar one. Neighboring chains are found to be irregularly oriented either parallel or antiparallel.

We report on significant developments of a high vacuum reflectometer (diffractometer) and spectrometer for soft x-ray synchrotron experiments which allows conducting a wide range of static and dynamic experiments. Although the chamber named ALICE was designed for the analysis of magnetic hetero- and nanostructures via resonant magnetic x-ray scattering, the instrument is not limited to this technique. The versatility of the instrument was testified by a series of pilot experiments. Static measurements involve the possibility to use scattering and spectroscopy synchrotron based techniques (photon-in photon-out, photon-in electron-out, and coherent scattering). Dynamic experiments require either laser or magnetic field pulses to excite the spin system followed by x-ray probe in the time domain from nano- to femtosecond delay times. In this temporal range, the demagnetization/remagnetization dynamics and magnetization precession in a number of magnetic materials (metals, alloys, and magnetic multilayers) can be probed in an element specific manner. We demonstrate here the capabilities of the system to host a variety of experiments, featuring ALICE as one of the most versatile and demanded instruments at the Helmholtz Center in Berlin-BESSY II synchrotron center in Berlin, Germany.

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