It's so easy! Direct trifluoromethanesulfanylation reactions remain difficult to perform because of the lack of reagents that are stable and easy to handle. Trifluoromethanesulfanamides are reagents which, in combination with readily available Grignard reagents, can be used by those without experience in fluorine chemistry to easily synthesize trifluoromethylthioethers.

Phase II ofCBr 4 is monoclinic, space group C2/c, with a = 21.43, b = 12.12, c = 21.02 ,/~,fl = 110.88 °, Z = 32. The structure was solved by direct methods and refined to R = 7.0% for 856 counter data. The monoclinic system can be converted into a pseudocubic system which facilitates the description of the structure.

No abstract