Hydrogen in Metals / Pd-Tb and Pd-Dy Alloys / p-C Isotherms / ThermodynamicsThe thermodynamic parameters for absorption of hydrogen by Pd-Tb alloys with up to 8.0 at.070 Tb and Pd-Dy alloys with up to 6.0 at.070. Dy have been determined from measurements of the pressure-composition isotherms at temperatures between 273 K and 473 K and hydrogen pressures up to 100 Torr. The results are compared with those of previously determined palladium-rare earth (RE = Sc, Y, Ce, Gd, Yb) alloys. The relative partial molar enthalpy of solution of hydrogen, AH:, at infinite dilution, and the standard enthalpy change, Milat. for / 3hydride formation for both Pd-Tb and Pd-Dy alloys become more exothermic with increasing Tb and Dy contents. The relative chemical potential, ApL, of dissolved hydrogen at infinite dilution at a given temperature in Pd-RE alloys decreases with a decrease of apparent H-H attractive interaction energy with several exceptions.With the exception of Pd-Ce alloys and some high solute metal content alloys, the stabilities of dissolved hydrogen at infinite dilution and 8-hydride phase for a series of Pd-RE-hydrogen systems are mainly governed by the lattice expansion of palladium by the substituent RE atoms which reduces the elastic strain energies necessary for hydrogen occupation of the octahedral interstices.
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