State-of-the-art electronic structure calculations (MR-CISD) are used to map five different dissociation channels of CH3Cl along the C-Cl coordinate: (i) CH3(X̃(2)A2″) + Cl((2)P), (ii) CH3(3s(2)A1') + Cl((2)P), (iii) CH3(+)((1)A1') + Cl(-)((1)S), (iv) CH3(3p(2)E') + Cl((2)P), and (v) CH3(3p(2)A2″) + Cl((2)P). By the first time these latter four dissociation channels, accessible upon VUV absorption, are described. The corresponding dissociation limits, obtained at the MR-CISD+Q level, are 3.70, 9.50, 10.08, 10.76, and 11.01 eV. The first channel can be accessed through nσ* and n3s states, while the second channel can be accessed through n(e)3s, n(e)3p(σ), and σ3s states. The third channel, corresponding to the CH3(+) + Cl(-) ion-pair, is accessed through n(e)3p(e) states. The fourth is accessed through n(e)3p(e), n(e)3p(σ), and σ3p(σ), while the fifth through σ3p(e) and σ(CH)σ* states. The population of the diverse channels is controlled by two geometrical spots, where intersections between multiple states allow a cascade of nonadiabatic events. The ion-pair dissociation occurs through formation of CH3(+)···Cl(-)and H2CH(+)···Cl(-) intermediate complexes bound by 3.69 and 4.65 eV. The enhanced stability of the H2CH(+)···Cl(-) complex is due to a CH···Cl hydrogen bond. A time-resolved spectroscopic setup is proposed to detect those complexes.

MR-CISD, MR-CISD+Q, and MR-AQCC calculations have been performed on the minima and transition states (corresponding to intramolecular proton transfer between the protonation sites) of the ground state of protonated nitrosamine and N,N-dimethylnitrosamine. Our highest level results (MR-AQCC/cc-pVTZ) for the smaller system indicate that protonation on the N amino (2a) is practically as favorable as the most favorable protonation on the O atom (1a). They also suggest that protonation on the nitroso N atom (2c) is ∼14.5 kcal/mol less favorable than 1a. Results obtained at the MR-CISD+Q/cc-pVTZ level indicate that the effect of methylation on the relative energies of the tautomers is, in order of importance, 2a > 2c and increases their energies by ∼17.5 and 4.8 kcal/mol, respectively. They also indicate that methylation alters significantly the intramolecular proton transfer barriers. The largest differences between the common geometric parameters of both systems have been found for 2a.

The mechanism of the O2 ⋅− and H2O2 reaction (Haber–Weiss) under solvent‐free conditions has been characterized at the DFT and CCSD(T) level of theory to account for the ease of this reaction in the gas phase and the formation of two different set of products (Blanksby et al., Angew. Chem. Int. Ed. 2007, 46, 4948). The reaction is shown to proceed through an electron‐transfer process from the superoxide anion to hydrogen peroxide, along two pathways. While the O3 ⋅− + H2O products are formed from a spin‐allowed reaction (on the doublet surface), the preferred products, O⋅−(H2O)+3O2, are formed through a spin‐forbidden reaction as a result of a favorable crossing point between the doublet and quartet surface. Plausible reasons for the preference toward the latter set are given in terms of the characteristics of the minimum energy crossing point (MECP) and the stability of an intermediate formed (after the MECP) in the quartet surface. These unique results show that these two pathways are associated with a bifurcation, yielding spin‐dependent products.

The effect of water molecule on the excited states of CH3Cl­(H2O), as compared to those of the isolated chloromethane, has been studied at the multireference configuration interaction with singles and doubles (MR-CISD), including extensivity corrections. Eight new Rydberg states are due to the water molecule but the common states of both systems are not severely altered. Potential energy curves of 23 singlet states along the C–Cl coordinate have also been computed at the MR-CISD level. The dissociation energy of the C–Cl bond decreases from ∼0.4 to 0.5 eV due to the water molecule. As for CH3Cl (de MedeirosV. C. de Medeiros, V. C. J. Am. Chem. Soc.2016138272280 a stable ion-pair has also been characterized. However, for CH3Cl­(H2O), this ion-pair is better described as a solvent-shared semi-ion-pair, CH3 +δ(H2O)­Cl–δ. This species is connected with three ionic dissociation channels, with two being due to the water molecule. The presence of these new ionic channels, particularly the lowest energy one, [H3C–O]+ + Cl–, raises a very important question of atmospheric relevance: can the interaction of chloroalkanes with water decrease its deleterious effect on the ozone layer? Several potentially new competing dissociation channels are also studied. The latter results can help to set up the most important states to be included in nonadiabatic dynamic calculations to study how the yields of the ionic channels change due to the water molecule.

The unusual O-coordination mode of nitrosamines to Fe(III) heme models has been observed in the bis(dimethylnitrosamine)(meso-tetraphenylporphyrinate)iron(III) cation. For the first time, this latter as well as the simpler bis(dimethylnitrosamine)(porphinate)iron(III) heme model cations have been studied through ab initio methods. The sextet, quartet, and doublet spin states of both cations have been studied through singlepoint calculations based on the experimental (X-ray) geometry. Their energies, charges, and spin densities have been analyzed. The obtained results (at the UHF/cc-pVDZ and ROHF/cc-pVDZ levels) indicate that the peripheral benzene rings are of secondary importance for the coordination of dimethylnitrosamine to the Fe(III) porphyrin core. The obtained energy ordering is sextet < quartet < doublet, at all computational levels. The UHF, ROHF, and UMP2 results indicate an excess of alpha spin density around the Fe atom, a low covalency for the FeAO bond and a substantial charge transfer to the Fe atom. Our best estimates [obtained at ROMP2 level with the mixed cc-pVDZ/cc-pVTZ-DK(Fe) basis set] for the energy differences (in eV) between the three spin states considered are 0.929 for the sextet-quartet gap and 0.812 for the quartetdoublet gap, which indicate that the spin crossover (at room temperature) is very unlikely. These results represent the substantial decrease in the uncorrelated values. The implications of spin contaminations at the UHF and UMP2 levels for subsequent geometry optimizations to be performed in the smaller cation have also been discussed.