Due to low availability of alternative technologies, rural communities are unable to comply with national wastewater discharge limits. This study tested the effectiveness of filter bed fortification with biochar on phosphorus removal. Water-tight down-flow beds of sand and gas concrete, constructed alongside a reference sand bed (all 0.8 m deep and 0.75 m(2) surface area), were topped with a 0.2 m biochar layer. Pre-treated domestic wastewater with mean concentrations of 6.4 mg/L [Formula: see text] and 142.6 NTU, was infiltrated at 4 cm/d hydraulic loading rate. Ultimately, the biochar-sand was relatively outstanding in turbidity reduction, achieving <5 NTU. The biochar-gas concrete exhibited superior performance in [Formula: see text] removal, trapping 32.3 g (40.2%), compared with 20.5 g (25.6%) and 15.5 g (19.3%) by biochar-sand and reference bed respectively. However, statistical analysis revealed a weak correlation between pH and biochar-gas concrete removal efficiency (r(2 )= 0.2). The relationship was stronger for biochar-sand [Formula: see text] (r(2 )= 0.5) than reference (r(2 )= 0.4) bed. Paired samples t-tests showed that incorporating biochar into the sand bed significantly (p = .04) improved its [Formula: see text] removal efficiency. In conclusion, sand bed fortification with biochar could be an important measure for improving P removal and wastewater clarification efficiency.

Contamination of water sources by inappropriately disposed poorly treated wastewater from countryside establishments is a worldwide challenge. This study tested the effectiveness of retrofitting sand (Sa)- and gas–concrete (GC)-packed reactors with biochar (C) in removing turbidity, dissolved organic carbon (DOC), phosphate (PO43−), and total phosphorus (Ptot) from wastewater. The down-flow reactors were each intermittently loaded with 0.063 L/d for 399 days. In general, all reactors achieved <3 NTU (Nephelometric Turbidity Units) effluent turbidity (99% efficiency). GC reactors dominated in inlet PO43− (6.1 mg/L) and DOC (25.3 mg/L) reduction, trapping >95% and >60%, respectively. Compared to Sa (PO43−: 35%, DOC: 52%), the fortified sand (SaC) filter attenuated more PO43− (>42%) and DOC (>58%). Student t-tests revealed that C significantly improved the Sa PO43− (p = 0.022) and DOC (p = 0.034) removal efficacy. From regression analysis, 53%, 81%, and 85% PO43− sorption variation in Sa, C, and SaC, respectively, were explained by variation in their effluent pH measures. Similarly, a strong linear correlation occurred between PO43− sorption efficiency and pH of fortified (r > 0.7) and reference (r = 0.6) GC filters thus suggesting chemisorption mechanisms. Therefore, whereby only sand may be available for treating septic tank effluents, fortifying it with biochar may be a possible measure to improve its efficacy.

Sand and gravel are widely applied for filtering pre- or primary-treated wastewater in small-scale wastewater treatment (SWT) systems. However, ecological materials continue to attract increasing interest in use as retrofits for achieving better performance in removing dissolved contaminants and recovering nutrients from wastewater. In this study, we assessed the plant availability and leachability of phosphorus (P) from sand (Sa) and gas concrete (GC) media previously fortified with biochar (BC) and used for phosphorus (P) removal in laboratory-scale packed bed reactors and field-scale constructed filter beds. Batch and leaching experiments were conducted, with distilled water and ammonium lactate (AL) solutions (1:20 solid-liquid (w/v) ratio) applied as extractants. In the findings, reference (Sa) and fortified (Sa-BC) sand filters leached 11.2 and 20.5 mg P kg respectively, to percolating water while the P seemed less likely to leach from GC systems. Extraction with AL showed that P retained in GC was plant-available and that GC could release up to 90 mg kg of the bound mass. These findings highlight the need to evaluate risks of nutrient leaching from filter media for SWT systems especially where groundwater and surface water are final recipients of such effluents. For greater sustainability of use of the media, the weakly bound P in media such as Sa and BC and strongly bound in media such as GC types of materials may be recovered by recycling the spent material to agriculture. However, this may require re-design of the treatment system especially with respect to particle size to make recycling technically feasible.