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The paper concerns thermal properties of epoxy/nanotubes composites for aircraft application. In this work, influence of carbon nanotubes on thermal stability, thermal conductivity, and crosslinking density of epoxy matrix was determined. Three kinds of nanotubes were used: non-modified with 1-and 1.5-lm length, and 1-lm length modified with amino groups. Scanning electron microscopy observations were done for examining dispersion of nanotubes in the epoxy matrix. Glass transition temperature (T g ) was readout from differential scanning calorimetry. From dynamic mechanical analysis, crosslinking density was calculated for epoxy and its composites. Also, thermogravimetric analysis was done to determine influence of nanotubes addition on thermal stability and decomposition process of composites. Activation energy was calculated from TGA curves by Flynn-WallOzawa method. Thermal diffusivity was also measured. SEM images proved the uniform dispersion of carbon nanotubes without any agglomerates. It was found that nanotubes modified with amino groups lead to the increase of epoxy matrix crosslinking density. The significant increase in T g was also observed. On the other hand, addition of carbon nanotubes leads to the decrease of thermal stability of polymer due to the increase of thermal diffusivity.

The aim of this work was to investigate the influence of different types of carbon filler on the thermal stability and flammability of rigid polyurethane foams. As a filler, multi-walled carbon nanotubes and graphite fakes were used. Scanning electron microscopy was used to observe the structure of foam and dispersion of nanofiller in polymer matrix. Thermal stability of these composites was determined by thermogravimetry analysis. Test was carried out under both nitrogen and air atmosphere. The degradation products were evaluated by thermogravimetry (TG) combined with infrared spectroscopy (TG-IR) measurements. The activation energy was measured by the Flynn-Wall-Ozawa method from the TG curves. Flammability tests like limiting oxygen index and smoke density were also measured. No significant changes in the thermal stability of the composites were observed. The activation energy of sample containing carbon filler increased. Based on TG-IR, one can notice that there were no differences in the emitted volatile products during thermal degradation. Carbon filler enhanced fire retardancy of polyurethane foam; however, graphite gives better results.

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The effect of the surface modification of carbon nanotubes on their dispersion in the epoxy matrix Functionalization of multi-walled carbon nanotubes (MWCNTs) has an effect on the dispersion of MWCNT in the epoxy matrix. Samples based on two kinds of epoxy resin and different weight percentage of MWCNTs (functionalized and non-functionalized) were prepared. Epoxy/carbon nanotubes composites were prepared by different mixing methods (ultrasounds and a combination of ultrasounds and mechanical mixing). CNTs modified with different functional groups were investigated. Surfactants were used to lower the surface tension of the liquid, which enabled easier spreading and reducing the interfacial tension. Solvents were also used to reduce the liquid viscosity. Some of them facilitate homogeneous dispersion of nanotubes in the resin. The properties of epoxy/nanotubes composites strongly depend on a uniform distribution of carbon nanotubes in the epoxy matrix. The type of epoxy resin, solvent, surfactant and mixing method for homogeneous dispersion of CNTs in the epoxy matrix was evaluated. The effect of CNTs functionalization type on their dispersion in the epoxy resins was evaluated on the basis of viscosity and microstructure studies.