Evolutionary innovations underlie the rise of diversity and complexity—the 2 long-term trends in the history of life. How does natural selection redesign multiple interacting parts to achieve a new emergent function? We investigated the evolution of a biomechanical innovation, the latch-spring mechanism of trap-jaw ants, to address 2 outstanding evolutionary problems: how form and function change in a system during the evolution of new complex traits, and whether such innovations and the diversity they beget are repeatable in time and space. Using a new phylogenetic reconstruction of 470 species, and X-ray microtomography and high-speed videography of representative taxa, we found the trap-jaw mechanism evolved independently 7 to 10 times in a single ant genus (Strumigenys), resulting in the repeated evolution of diverse forms on different continents. The trap mechanism facilitates a 6 to 7 order of magnitude greater mandible acceleration relative to simpler ancestors, currently the fastest recorded acceleration of a resettable animal movement. We found that most morphological diversification occurred after evolution of latch-spring mechanisms, which evolved via minor realignments of mouthpart structures. This finding, whereby incremental changes in form lead to a change of function, followed by large morphological reorganization around the new function, provides a model for understanding the evolution of complex biomechanical traits, as well as insights into why such innovations often happen repeatedly.
In the nanoregime, chemical species can reorganize in ways not predicted by their equilibrium bulk behavior. Here, we engineer Ni-Cr nanoalloys at the magnetic end of their compositional range (i.e., 0-15 at. % Cr), and we investigate the effect of Cr incorporation on their structural stability and resultant magnetic ordering. To ensure their stoichiometric compositions, the nanoalloys are grown by cluster beam deposition, a method that allows one-step, chemical-free fabrication of bimetallic nanoparticles. While full Cr segregation toward nanoparticle surfaces is thermodynamically expected for low Cr concentrations, metastability occurs as the Cr dopant level increases in the form of residual Cr in the core region, yielding desirable magnetic properties in a compensatory manner. Using nudged elastic band calculations, residual Cr in the core is explained based on modifications in the local environment of individual Cr atoms. The resultant competition between ferromagnetic and antiferromagnetic ordering gives rise to a wide assortment of interesting phenomena, such as a cluster-glass ground state at very low temperatures and an increase in Curie temperature values. We emphasize the importance of obtaining the commonly elusive magnetic nanophase diagram for M-Cr (M = Fe, Co, and Ni) nanoalloys, and we propose an efficient single-parameter method of tuning the Curie temperature for various technological applications.
We propose an approach to coalescence studies that encompasses the random nature of nanoparticle deposition, which results in a statistical cancellation of individual sintering mechanisms. We present a rigorous, yet simple and intuitive, analytical method that describes the average coalescence behaviour of nanoparticles, regardless of constituent element or crystallinity, emphasizing only the predominant coalescence dependencies on temperature and size-dependent nanoparticle melting points. We assessed our model using molecular dynamics (MD) computer simulations of dissimilar systems, and found remarkable agreement between its predictions and the MD results. Its simplicity makes our model a suitable starting point for the development of a meso-scale simulation technique that can describe the growth of porous films and allow for their bespoke design.
A new approach on the synthesis of Si anodes for Li‐ion batteries is reported, combining advantages of both nanoparticulated and continuous Si films. A multilayered configuration prototype is proposed, comprising amorphous Si arranged in nanostructured, mechanically heterogeneous films, interspersed with Ta nanoparticle scaffolds. Particular structural features such as increased surface roughness, nanogranularity, and porosity are dictated by the nanoparticle scaffolds, boosting the lithiation process due to fast Li diffusion and low electrode polarization. Consequently, a remarkable charge/discharge speed is reached with the proposed anode, in the order of minutes (1200 mAh g−1 at 10 C). Moreover, nanomechanical heterogeneity self‐limits the capacity at intermediate charge/discharge rates; as a consequence, exceptional cycleability is observed at 0.5 C, with 100% retention over 200 cycles with 700 mAh g−1. Higher capacity can be obtained when the first cycles are performed at 0.2 C, due to the formation of microislands, which facilitate the swelling of the active Si. This study indicates a method to tune the mechanical, morphological, and electrochemical properties of Si electrodes via engineering nanoparticle scaffolds, paving the way for a novel design of nanostructured Si electrodes for high‐performance energy storage devices.
Cr-surface segregation is a main roadblock encumbering many magneto-biomedical applications of bimetallic M-Cr nanoalloys (where M = Fe, Co and Ni). To overcome this problem, we developed Ni95Cr5:Ag nanocomposite as a model system, consisting of non-interacting Ni95Cr5 nanoalloys (5 ± 1 nm) immersed in non-magnetic Ag matrix by controlled simultaneous co-sputtering of Ni95Cr5 and Ag. We employed Curie temperature (TC) as an indicator of phase purity check of these nanocomposites, which is estimated to be around the bulk Ni95Cr5 value of 320 K. This confirms prevention of Cr-segregation and also entails effective control of surface oxidation. Compared to Cr-segregated Ni95Cr5 nanoalloy films and nanoclusters, we did not observe any unwanted magnetic effects such as presence Cr-antiferromagnetic transition, large non-saturation, exchange bias behavior (if any) or uncompensated higher TC values. These nanocomposites films also lose their unique magnetic properties only at elevated temperatures beyond application requirements (≥800 K), either by showing Ni-type behavior or by a complete conversion into Ni/Cr-oxides in vacuum and air environment, respectively.
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