Experimental procedures are described for producing negative ions of fluoro and trifluoromethyl derivatives of C 60 in the vapor phase and characterizing them by Knudsen-cell mass spectrometry. Some common aspects of the formation of such ions are established, and the associated ion-molecule equilibria are investigated. Electron affinity data are presented for C 60 (CF 3 ) 2 n molecules. It is shown that, upon ionization, the fluorofullerenes tend to loose one or several fluorine atoms.
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