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Emission of volatile organic compounds (VOCs) produced during composting of different organic wastes (source-selected organic fraction of municipal solid wastes (OFMSW), raw sludge (RS) and anaerobically digested wastewater sludge (ADS) and animal by-products (AP)) and its subsequent biofiltration have been studied.Composting was performed in a laboratory scale composting plant (30 l) and the exhaust gases generated were treated by means of a compost biofilter. VOCs concentration in the composting exhaust gases for each composting process ranged from 50 to 695 mg C·m -3 for OFMSW

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A tailor-made apparatus called ammoniometer, which is a batch mode respirometer applied to the study of ammonia biodegradation in biofilter media, has been used to evaluate adsorption, absorption, and biodegradation in five different organic materials (compost, coconut fibre, bark, pruning wastes, and peat) obtained from full-scale biofilters in operation in several waste treatment plants. The results showed that absorption could be represented by a Henry's law linear equation, with values of the Henry coefficient significantly higher (from 1,866 to 15,320) than that of pure water (1,498). Adsorption data were successfully fitted to Langmuir and Freundlich isotherms and maximum adsorption capacity varies from 1.06 to 1.81 mg NH(3)/g dry media. Ammonia biodegradation rates for each organic material were also calculated. Biodegradation rates varied from 0.67 to 7.82 mg NH(3)/kg media/d depending on the material tested. The data obtained showed important differences in the behaviour of the biofilter organic media, which has important implications in the design and modelling of these systems.

Respirometric index (determined at 55ºC) and maturity grade appeared to be the most reliable tests to follow the biological activity of the OFMSW composting. On the other hand, routine parameters such as temperature, oxygen content and moisture showed no significant differences among the different inoculation levels tested in the composting process.

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