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Analysis of microplastic particles in environmental samples needs sophisticated techniques and is time intensive due to sample preparation and detection. Alternatives to the most common (micro-) spectroscopic techniques, Fourier transform infrared and Raman spectroscopy, are thermoanalytical methods, in which specific decomposition products can be analyzed as marker compounds for different kinds of plastic types and mass contents. Thermal extraction desorption gas chromatography−mass spectrometry allows the fast identification and quantification of MP in environmental samples without sample preparation. Whereas to date only the analysis of thermoplastic polymers has been realized, this is the first time that even the analysis of tire wear (TW) content in environmental samples has been possible. Various marker compounds for TW were identified. They include characteristic decomposition products of elastomers, antioxidants, and vulcanization agents. Advantages and drawbacks of these marker substances were evaluated. Environmental samples from street runoff were exemplarily investigated, and the results are presented.

The issues surrounding micro- and nanoplastics (MPs and NPs) are gaining importance as the knowledge about their distribution and impacts on the environment and human health grows. In order to gain a better understanding about the occurrence of those plastic particles and the pollution of different freshwater systems, the project, “Rheines Wasser” were conducted. This project investigated the entire 1,232.7 km-length of Europe’s Rhine River, which serves an important function for both transportation and water supply for several million people. Surface water samples of the river were filtered and the microplastic (MP) particles were detected by Fourier transform infrared microscopy. At several sample stations, different concentrations of MP-particles were found, ranging from 5 to 5326 particles/m3.

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