Spray carrier pH affects the solubility of sulfonylurea herbicides and, therefore, could affect absorption and subsequent translocation of these compounds in weeds. Trifloxysulfuron is a sulfonylurea herbicide developed for POST weed control in cotton, sugarcane, and turfgrass with a pKa of 4.81. The objective of this study was to evaluate the absorption and translocation of foliar-applied 14C-trifloxysulfuron in Palmer amaranth and Texasweed at pH 5, 7, and 9 over a period of 4 to 72 h after treatment (HAT). For absorption, effects of time, species, and pH were significant. Absorption averaged over species and pH increased logarithmically from 4 to 72 HAT. Absorption was greater for Palmer amaranth (88%) than for Texasweed (29%) when averaged over time and pH. Absorption averaged over species and time increased in the order of pH 5 (52%) < pH 9 (60%) = pH 7 (61%). Consequently, this translated into greater translocation of 14C-trifloxysulfuron in Texasweed when sprayed with the higher pH spray solutions. These data indicate that absorption and translocation of trifloxysulfuron in some weed species may be enhanced by increasing the pH of the spray solution by 2 pH units above the pKa.
Field research was conducted at three locations in Mississippi to evaluate CGA-277476 tank mixtures with four broadleaf herbicides for possible improvement of broadleaf weed control. Tank mixtures in this research were typically additive, although some instances of antagonism were noted. Control of morningglory (Ipomoea) species and hemp sesbania (Sesbania exaltata) was not consistently improved by the addition of acifluorfen, chlorimuron, fomesafen, or imazaquin to 59 or 79 g ai/ha CGA-277476. However, when a large population of weeds was present, the addition of acifluorfen, chlorimuron, or fomesafen to 59 or 79 g/ha CGA-277476 improved control over CGA-277476 alone. Prickly sida (Sida spinosa) was not controlled more than 68% with any treatment in this study; however, horse purslane (Trianthema portulacastrum) was controlled at least 90% with either 79 g/ha CGA-277476 alone or tank-mixed with acifluorfen, fomesafen, chlorimuron, or imazaquin. The addition of CGA-277476 to acifluorfen or fomesafen did not improve control over acifluorfen or fomesafen alone on any of the weeds evaluated; however, the addition of CGA-277476 to imazaquin improved hemp sesbania control over imazaquin alone. Tank mixtures did not result in yields greater than CGA-277476 alone in areas with moderate weed pressure, whereas in areas with severe weed pressure, tank mixtures improved soybean (Glycine max) yield over CGA-277476 alone.
Field experiments were conducted at three Mississippi locations to evaluate potential antagonism when postemergence graminicides were tank-mixed with CGA-277476 and to determine if the antagonism could be overcome with an increase in graminicide rate. At all locations when the 1X rate of clethodim, fluazifop-P, or quizalofop was tank-mixed with 79 g ai/ ha CGA-277476, johnsongrass, broadleaf signalgrass, and barnyardgrass control was reduced 5 to 30%. When the graminicide rates were increased to 1.5X, antagonism was still present for fluazifop-P and quizalofop. However, 156 g ai/ha clethodim overcame the antagonism when tank-mixed with 79 g/ha CGA-277476 compared to 105 g/ha clethodim. CGA-277476 alone controlled barnyardgrass and broadleaf signalgrass 38 to 63% and johnsongrass 60 to 85%. There were no differences in soybean yields with graminicides applied alone or tank-mixed with CGA-277476.
The surface runoff potential of trifloxysulfuron {N-[(4,6-dimethoxy-2-pyrimidinyl)carbamoyl]-3-(2,2,2-trifluoroethoy)-pyridin-2-sulfonamide sodium salt} in cotton (Gossypium hirsutum L.) production systems has not been evaluated. The objectives of this study were to (i) determine sorption/desorption coefficients for trifloxysulfuron; (ii) quantify foliar washoff of trifloxysulfuron when applied to cotton at the five-leaf stage; and (iii) determine the surface runoff potential of trifloxysulfuron when applied to cotton at the five-leaf stage and to bare soil. Freundlich sorption and desorption coefficients were 1.15 and 1.22, respectively. Sorption data indicated that trifloxysulfuron was moderately sorbed to soil and that it will be transported primarily in the dissolved phase of surface runoff. Foliar washoff studies revealed that approximately 91% of trifloxysulfuron applied to cotton at the five-leaf stage was available for washoff 72 h after application. Simulated rainfall (7.5 cm h-1) applied 1 day after herbicide application (7.9 g ha-1) resulted in average concentrations of trifloxysulfuron in surface runoff water of 0.8 microg L-1 for bare plots and 1.3 microg L-1 for cotton plots. Cumulative trifloxysulfuron losses in surface runoff from bare plots and cotton plots were 0.13 and 0.21 g ha-1, respectively. These values correspond to fractional losses of 1.7% for bare plots and 2.7% for cotton plots. Greater runoff losses of trifloxysulfuron from cotton plots were attributed to foliar washoff. Trifloxysulfuron runoff losses may be curtailed if the herbicide is applied early postemergence when canopy coverage is minimal, thereby reducing the potential for foliar washoff.
Soil-applied herbicides alone or followed by postemergence (POST) applications of CGA-277476 were evaluated for season-long weed control in soybean. Common cocklebur, hemp sesbania, and pitted morningglory control was not consistently improved with a soil-applied herbicide followed by a POST application of 79 g ai/ha CGA-277476. However, in locations with heavy weed pressure, a tank-mix of chlorimuron + metribuzin + trifluralin or imazaquin + pendimethalin followed by CGA-277476 improved common cocklebur, hemp sesbania, and pitted morningglory over CGA-277476 alone. Sequential application of CGA-277476 following SAN 582 improved weed control over SAN 582 alone. When weed pressure was not severe, there were no differences in control from CGA-277476 alone or following soil-applied herbicides. A POST application of CGA-277476 following soil-applied herbicides did not consistently improve soybean yield over CGA-277476 alone. Yield from soybean treated with SAN 582 was improved when CGA-277476 was applied. In contrast, when chlorimuron + metribuzin + trifluralin or imazaquin + pendimethalin were applied at planting, yield was similar with or without POST application of CGA-277476.
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