Recognizing whether a planet can support life is a primary goal of future exoplanet spectral characterization missions, but past research on habitability assessment has largely ignored the vastly different conditions that have existed in our planet's long habitable history. This study presents simulations of a habitable yet dramatically different phase of Earth's history, when the atmosphere contained a Titan-like, organic-rich haze. Prior work has claimed a haze-rich Archean Earth (3.8–2.5 billion years ago) would be frozen due to the haze's cooling effects. However, no previous studies have self-consistently taken into account climate, photochemistry, and fractal hazes. Here, we demonstrate using coupled climate-photochemical-microphysical simulations that hazes can cool the planet's surface by about 20 K, but habitable conditions with liquid surface water could be maintained with a relatively thick haze layer (τ ∼ 5 at 200 nm) even with the fainter young Sun. We find that optically thicker hazes are self-limiting due to their self-shielding properties, preventing catastrophic cooling of the planet. Hazes may even enhance planetary habitability through UV shielding, reducing surface UV flux by about 97% compared to a haze-free planet and potentially allowing survival of land-based organisms 2.7–2.6 billion years ago. The broad UV absorption signature produced by this haze may be visible across interstellar distances, allowing characterization of similar hazy exoplanets. The haze in Archean Earth's atmosphere was strongly dependent on biologically produced methane, and we propose that hydrocarbon haze may be a novel type of spectral biosignature on planets with substantial levels of CO2. Hazy Archean Earth is the most alien world for which we have geochemical constraints on environmental conditions, providing a useful analogue for similar habitable, anoxic exoplanets. Key Words: Haze—Archean Earth—Exoplanets—Spectra—Biosignatures—Planetary habitability. Astrobiology 16, 873–899.

In 2017, western Canadian wildfires injected smoke into the stratosphere that was detectable by satellites for more than 8 months. The smoke plume rose from 12 to 23 kilometers within 2 months owing to solar heating of black carbon, extending the lifetime and latitudinal spread. Comparisons of model simulations to the rate of observed lofting indicate that 2% of the smoke mass was black carbon. The observed smoke lifetime in the stratosphere was 40% shorter than calculated with a standard model that does not consider photochemical loss of organic carbon. Photochemistry is represented by using an empirical ozone-organics reaction probability that matches the observed smoke decay. The observed rapid plume rise, latitudinal spread, and photochemical reactions provide new insights into potential global climate impacts from nuclear war.

Terrestrial planets in the habitable zones (HZs) of low-mass stars and cool dwarfs have received significant scrutiny recently Transit spectroscopy of such planets with JWST represents our best shot at obtaining the spectrum of a habitable planet within the next decade. As these planets are likely tidal-locked, improved 3D numerical simulations of such planetary atmospheres are needed to guide target selection. Here we use a 3-D climate system model, updated with new water-vapor absorption coefficients derived from the HITRAN 2012 database, to study ocean covered planets at the inner edge of the HZ around late-M to mid-K stars (2600K ≤ T ef f ≤ 4500K). Our results indicate that these updated water-vapor coefficients result in significant warming compared to previous studies, so the inner HZ around M-dwarfs is not as close as suggested by earlier work. Assuming synchronously rotating Earth-sized and Earth-massed planets with background 1 bar N 2 atmospheres, we find that planets at the inner -2 -HZ of stars with T ef f > 3000K undergo the classical "moist-greenhouse" (H 2 O mixing ratio > 10 −3 in the stratosphere) at significantly lower surface temperature (∼ 280K) in our 3-D model compared with 1-D climate models (∼ 340K). This implies that some planets around low mass stars can simultaneously undergo water-loss and remain habitable. However, for star with T ef f ≤ 3000K, planets at the inner HZ may directly transition to a runaway state, while bypassing the moist greenhouse water-loss entirely. We analyze transmission spectra of planets in a moist greenhouse regime, and find that there are several prominent H 2 O features, including a broad feature between 5-8 microns, within JWST MIRI instrument range. Thus, relying only upon standard Earth-analog spectra with 24-hour rotation period around M-dwarfs for habitability studies will miss the strong H 2 O features that one would expect to see on synchronously rotating planets around M-dwarf stars, with JWST.