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Production planning in the petrochemical industry requires a model that can account for the different interactions, needs, and features and provide at the same time suitable mathematical representation. In this work, a model with an environmental objective is presented. The system is formulated as a mixed-integer linear programming model where new value-added products are produced from the basic feedstock chemicals. From the superstructure of the technology alternatives, the optimal set of processes is selected with the objective function of sustainability. The quest for pollution prevention and increased pressure and demand for environmental considerations makes sustainability an important objective function. In this study, sustainability is quantified by a health index of the chemicals and increasing profit represented by processadded value. The model is applied to the case study of planning the development of the Kuwait petrochemical industry. Results give an optimal structure for the development and prove that simple indicators can represent sustainability, giving good results in selecting environmentally friendly processes and at the same time being profitable.

The reaction rates of CO2 in an aqueous blend of amine solutions of N‐(2‐hydroxethyl)piperazine (N‐HEPZ) and 2‐amino‐2‐hydroxymethyl‐1,3‐propanediol (AHPD) at 298 K were investigated in a concentration range of 0.0025–0.03 kmol m–3 N‐HEPZ with a blend of 1 kmol m–3 AHPD. The reaction was modeled using a termolecular reaction mechanism with a rate of 12 971 m3kmol–1s–1. The results indicate that the blended aqueous solution of N‐HEPZ and AHPD is a potential candidate as an alternative solvent for CO2 absorption, where the sterically hindered AHPD increases the CO2 capacity and the reaction rate is enhanced by the promoter, N‐HEPZ.

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