Careful selection of photocaging approaches is critical to achieve fast and well synchronized reaction initiation and perform successful time-resolved structural biology experiments. This review summarizes the best characterized and most relevant photocaging groups previously described in the literature. It also provides a walkthrough of the essential factors to consider in designing a suitable photocaged molecule to address specific biological questions, focusing on photocaging groups with well characterized spectroscopic properties. The relationships between decay rates (k in s−1), quantum yields (φ) and molar extinction coefficients (ɛmax in M
−1 cm−1) are highlighted for different groups. The effects of the nature of the photocaged group on these properties is also discussed. Four main photocaging scaffolds are presented in detail, o-nitrobenzyls, p-hydroxyphenyls, coumarinyls and nitrodibenzofuranyls, along with three examples of the use of this technology. Furthermore, a subset of specialty photocages are highlighted: photoacids, molecular photoswitches and metal-containing photocages. These extend the range of photocaging approaches by, for example, controlling pH or generating conformationally locked molecules.
This study aims to find out whether exchange rate volatility affects real estate domestic house prices in Ghana. To this end, a 32 years secondary data from World Development Indicators (WDI) and data from Real Estate Developers in Ghana are employed for the study. The study employs Autoregressive distributed lags (ARDL) bounds testing of cointegration t o test the null hypothesis that exchange rate volatility has n o impact on real estate housing prices. The study finds that real estate price is cointegrated with remittances, exchange rate and inflation. The long run equilibrium is stable and significant. Exchange rates d o not cause changes in real estate prices in both short and long run. Similarly past prices of real estate d o not have impact on current house prices. Rather, remittances positively cause real estate prices. Inflation on its part has a negative impact on real estate prices. It is therefore concluded that, volatility in the exchange rate between the cedi and other trading currencies does not predict changes in real estate prices.
In the wave of raging debate, even on the floor of parliament, as to whether it would be expedient to commercialize Bikes’ usage in Ghana, it is important to look at its benefits or otherwise. Hence, the study sought to show whether Ghana should legalize the commercial use of motor cycles and tricycles operations. The design was a descriptive study which used quantitative tool to show public acceptance or rejection of commercializing the use of motorcycles and tricycles in Ghana. The study was based on the use of questionnaires for the data collection and were analyzed using Microsoft Excel. The sample population considered was Five (5) Regions in Ghana which are Central, Greater Accra, Bono, Bono East and Northern Regions. Questionnaires of 460 were drawn for the study. It was found out, among others, that many of the riders do not possess licenses; riders are aware of robbery incidents perpetuated by their colleagues; police harassments and passenger pressure are strong reasons for not observing traffic regulations; unfavorable road architecture; the activity is a good source of income. It was therefore recommended that, the okada/pragia/keke/motor king/motor kia operations should be legalized for commercial use with regulations and strict compliance by actors or operators.
In the wave of raging debate, even on the floor of parliament, as to whether it would be expedient to commercialize Bikes’ usage in Ghana, it is important to look at its benefits or otherwise. Hence, the study sought to show whether Ghana should legalize the commercial use of motor cycles and tricycles operations. The design was a descriptive study which used quantitative tool to show public acceptance or rejection of commercializing the use of motorcycles and tricycles in Ghana. The study was based on the use of questionnaires for the data collection and were analyzed using Microsoft Excel. The sample population considered was Five (5) Regions in Ghana which are Central, Greater Accra, Bono, Bono East and Northern Regions. Questionnaires of 460 were drawn for the study. It was found out, among others, that many of the riders do not possess licenses; riders are aware of robbery incidents perpetuated by their colleagues; police harassments and passenger pressure are strong reasons for not observing traffic regulations; unfavorable road architecture; the activity is a good source of income. It was therefore recommended that, the okada/pragia/keke/motor king/motor kia operations should be legalized for commercial use with regulations and strict compliance by actors or operators.
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