A multivariate statistical analysis was performed on multi-element soil geochemical data from the Koda Hill-Bulenga gold prospects in the Wa-Lawra gold belt, northwest Ghana. The objectives of the study were to define gold relationships with other trace elements to determine possible pathfinder elements for gold from the soil geochemical data. The study focused on seven elements, namely, Au, Fe, Pb, Mn, Ag, As and Cu. Factor analysis and hierarchical cluster analysis were performed on the analyzed samples. Factor analysis explained 79.093% of the total variance of the data through three factors. This had the gold factor being factor 3, having associations of copper, iron, lead and manganese and accounting for 20.903% of the total variance. From hierarchical clustering, gold was also observed to be clustering with lead, copper, arsenic and silver. There was further indication that, gold concentrations were lower than that of its associations. It can be inferred from the results that, the occurrence of gold and its associated elements can be linked to both primary dispersion from underlying rocks and secondary processes such as lateritization. This data shows that Fe and Mn strongly associated with gold, and alongside Pb, Ag, As and Cu, these elements can be used as pathfinders for gold in the area, with ferruginous zones as targets
ABSTRACT:A regolith map for the Lawra Belt has been developed by categorizing the regolithlandform units by processing and interpreting remote sensing data. Regolith landform units were extracted from Landsat band ratios 3/1 and 5/4 to map ferruginous saprolite and lags; band ratio 5/7 was used to identify residual regolith and band ratio 4/2 was employed to separate ferruginous units from non-ferruginous regolith.Additional regolith landform units' discrimination was provided by compiling and interpolating radiometric data particularly for Landsat TM poorly defined areas.SRTM images were used to mark out the extent of the alluvial plains. High topographical terrains were marked from DEM image to represent the residual areas.Regolith landform unit (RLU) map that showed residual (relict and erosional), ferruginous, and depositional domains of the Lawra Belt was developed by superimposing the extractions made from the remote sensed data. Interpretive map generated from the remote sensed image analysis was validated by first creating a non-genetic regolith map through ground truth survey. The non-genetic map based on A C C E P T E D M A N U S C R I P T ACCEPTED MANUSCRIPT2 | P a g e spatial distributions of the different regolith mapping units were classified on genetic classes or regimes based on regolith-landform similarities to develop a genetic map.The interpretive and the genetic map were superimposed to develop the regolith map for the Lawra Belt. The inliers and outliers presenting compositional overlaps within broad regolith classes were rectified from the field mapping information. The combined approach of image analysis and the ground truth mapping grouped the regolith of Lawra Belt into ferruginous (F), relict (R), erosional (E) and depositional (D) regimes.
Ten samples of 100 g weight were subsampled from 1400 g of the clay balls from which the contained trace element levels were determined by X-ray fluorescence technique. The results of trace elements in the clay balls were calibrated using certified reference materials "MAJMON" and "BH-1." The results showed elevated concentrations but with different concentration levels in the regions, particularly with arsenic, chromium, cobalt, Cs, Zr and La. These trace elements contained in the clay balls are known to be hazardous to human health. Thence the relatively high concentrations of these listed trace elements in clay balls in the three regions, namely Ashanti, Upper East and Volta, which are widely sold in markets in Ghana, could present negative health impact on consumers if consumed at 70 g per day or more and on regular basis. On the basis of these, the study concludes an investigation to establish breakeven range for trace element concentrations in the clay balls as it has been able to demonstrate the uneven and elevated values in them. The standardized safe ranges of trace elements will make the practice safer for the people that ingest clay balls in Ghana.
Environmental geochemistry classifies elements into essential, non-essential and toxic elements in relationship to human health. To assess the environmental impact of mining at Datoko-Shega area, the distributions and concentrations of trace elements in stream sediments and soil samples were carried out. X-ray fluorescence analytical technique was used to measure the major and trace element concentrations in sediments and modified fire assay absorption spectrometry in soils. The results showed general depletion of major elements except titanium oxide (TiO2) compared to the average crustal concentrations. The retention of TiO2 at the near surface environment probably was due to the intense tropical weathering accompanied by the removal of fine sediments and soil fractions during the harmattan season by the dry north-east trade winds and sheet wash deposits formed after flash floods. The results also showed extreme contamination of selenium (Se), cadmium (Cd) and mercury (Hg), plus strong contaminations of arsenic (As) and chromium (Cr) in addition to moderate contamination of lead (Pb) in the trace element samples relative to crustal averages in the upper continental crust. However Hg, Pb and Cd concentrations tend to be high around the artisanal workings. It was recognised from the analysis of the results that the artisanal mining activity harnessed and introduces some potentially toxic elements such as Hg, Cd and Pb mostly in the artisan mine sites. But the interpretation of the trace element data thus invalidates the elevation of As concentrations to be from the mine operations. It consequently noticed As values in the mine-impacted areas to be similar or sometimes lower than As values in areas outside the mine sites from the stream sediment results.
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