This study aims to determine the rate of chemical denudation and the relationships between dominant geochemical reactions operating in the proglacial and subglacial environments of the polythermal glacier Werenskioldbreen (SW Svalbard) during an entire ablation season. Water sampling for major ion chemistry was performed at a proglacial hydrometric station and from subglacial outflows from May to September 2011. These data were combined with measurements of discharge and supraglacial ablation rates. The slopes and intercepts in bestfit regressions of [*Ca 2+ +*Mg 2+ vs. *SO 4 2-] and [HCO 3 vs. *SO 4 2-] in meltwater from icemarginal subglacial channels were close to the stoichiometric parameters of sulfide oxidation and simple hydrolysis coupled to carbonate dissolution (*concentrations corrected for input of sea-salt). This shows that these relationships predominates the meltwater chemistry. Our findings also show that sulfide oxidation is a better indicator of the configuration of subglacial drainage systems than, for instance, Na + and K +. In the proglacial area and in sub-artesian outflows, the ion associations represent sulfide oxidation but other processes such as ion exchange and dissolution of Ca and Mg efflorescent salts may also contribute to the solute variations. These processes may cause enhanced fluxes of Ca 2+ and HCO 3 from glacierised basins during the early ablation and peak flow seasons as the proglacial salts re-dissolve. The overall chemical denudation rate in the basin for 2011 (ranging from 1601 and 1762 meq m-2 yr-1 (121.9 and 132.2 t km-2 yr-1)) was very high when compared to other Svalbard valley glaciers suggesting that the high rate of chemical denudation was mostly caused by the high rates of discharge and ablation. Chemical weathering intensities (876 and 964 meq m-3 yr-1) exceeded previously reported intensities in Svalbard.

Abstract:The results from a hydrological monitoring program of Breelva basin (Spits− bergen, Svalbard) have been analysed to improve the understanding of the Werenskiöld Glacier system's functioning in the High Arctic. Hydrographs of a 44 km 2 river basin (27 km 2 of which was covered by a glacier) were analysed for the period 2007-2012. Sea− sonal discharge fluctuations were linked to glacier ablation and meteorological parameters, including atmospheric circulation types. A dichotomy was found in the discharge peaks generation during the hydrologically active season, with the main role played by snow and ice melt events during its first part and the rainfall regime dominating its second part. Foehn type strong winds played a significant role in the generation of ablation type floods (e.g. in August 2011). A simple classification of the runoff regime was applied to the examined six−year period, resulting in the identification of its three types: the ablation type (dominant in 2007 and 2009), the rainfall type (in the years 2011-2012), and the mixed type (during 2008 and 2010). According to publications the river flow season in Spitsbergen begins in June and end with freeze−up in September or at the beginning of October. Recently, this sea− son for Breelva tend to be extended with the mid−May onset and end in the second part of October. A multiannual trend was noted that reflects a growing importance of rainfalls, especially in September. Rainfall waters play a more distinct role in outflow from the Breelva catchment recently.