The aluminium (Al) cycle in glacierised basins has not received a great deal of attention in studies of biogeochemical cycles. As Al may be toxic for biota, it is important to investigate the processes leading to its release into the environment. It has not yet been ascertained whether filterable Al (passing through a pore size of 0.45 μm) is incorporated into biogeochemical cycles in glacierised basins. Our study aims to determine the relationship between the processes bringing filterable Al and glacier‐derived filterable nutrients (particularly Fe and Si) into glacierised basins. We investigated the Werenskiöldbreen basin (44.1 km2, 60% glacierised) situated in SW Spitsbergen, Svalbard. In 2011, we collected meltwater from a subglacial portal at the glacier front and at a downstream hydrometric station throughout the ablation season. The Al concentration, unchanged between the subglacial system and proglacial zone, reveals that aluminosilicate weathering is a dominant source of filterable Al under subglacial conditions. By examining the Al:Fe ratio compared with pH and the sulphate mass fraction index, we found that the proton source for subglacial aluminosilicate weathering is mainly associated with sulphide oxidation and, to a lesser degree, with hydrolysis and carbonation. In subglacial outflows and in the glacial river, Al and Fe are primarily in the forms of Al(OH)4‐ and Fe(OH)3. The annual filterable Al yield (2.7 mmol m‐2) was of a magnitude similar to that of nutrients such as filterable Fe (3.0 mmol m‐2) and lower than that of dissolved Si (18.5 mmol m‐2). Our results show that filterable Al concentrations in meltwater are significantly correlated to filterable and dissolved glacier‐derived nutrients (Fe and Si, respectively) concentrations in glaciers worldwide. We conclude that a potential bioavailable Al pool derived from glacierised basins may be incorporated in biogeochemical cycles, as it is strongly related to the concentrations and yields of glacier‐derived nutrients.
A unique data set of suspended sediment transport from the Breelva, which drains the Werenskioldbreen (Southwestern Spitsbergen), is reported for the period 2007–2012. This basin is thoroughly described hydrologically, glaciologically, and chemically. However, until now there was a lack of full recognition of mechanical denudation. This study extends the information on quantitative suspended sediment load (SSL), amounting to 37.30–130.94 kt per year, and also underlines the importance of its modification by high discharge events, triggered by intense snowmelt or heavy rainfall. The large floods during the hydrologically active season transported even 83% of the total SSL. The variability of the SSL is controlled by glacial storage and release mechanisms. Particularly interesting is the second half of the hydrologically active season when intense rainfall events plays a key role in shaping the sediment supply pattern. The main source of fine mineral matter is the basal moraine, drained by subglacial outflows. Their higher mobilization occurs when the hydrostatic pressure increases, often as a result of rainwater supply to the glacier system. An increasing precipitation trend for Hornsund fjord region determines a positive trend predicted for sediment flux.
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