The Dinaride Ophiolite Belt formed from the Jurassic part of the Neotethys. The investigated Ozren ophiolite complex in Bosnia and Herzegovina consists of peridotites, plagioclase peridotites, plagiogranites, troctolites and other gabbroic rocks, and fewer basalts. Lherzolites and harzburgites contain corroded ortho- and clinopyroxene1 porphyroclasts enclosed in the olivine matrix. The boundaries between olivine aggregates and pyroxene1 and spinel1 are infilled by medium-grained undeformed aggregates of clinopyroxene2, less orthopyroxene2, spinel2, and often clinopyroxene3-spinel3 symplectites. These textures indicate the final crystallization of peridotite in subsolidus conditions. Partial dissolution of deformed pyroxene1 porphyroclasts and coarse-grained spinel1 most likely occurred due to their reaction with the rest melt present in the grain boundaries. The Al decrease from pyroxene1 to pyroxene2 and 3, or the Cr decrease and Al increase from spinel1 to spinel2 and 3 is characteristic. Peridotites are associated with inferred remnants of a gabbro-dolerite layer, whereas basalts and radiolarites occur as rare dm-size fragments in an ophiolitic breccia. Troctolites display interstitial crystallization of plagioclase, clinopyroxene, less Na-Ti-rich amphiboles, and phlogopite in the olivine-spinel matrix, indicating the replacive character of impregnating melt within the dunite layers. Clinopyroxene-plagioclase-ilmenite-±amphibole gabbroic and fewer basaltic dykes in peridotites formed due to subridge extension, mantle thinning, and the deeper mantle melting. Iron-enriched olivines occur in the peridotite-dyke interfaces and troctolites. Hydrated ultramafics and mafics contain amphiboles, biotite, phlogopite, clinozoisite, epidote, and chlorite aggregates. Estimated magmatic to subsolidus T from peridotite two-pyroxene thermometry are 1000–850 °C, for the spinel facies. Ca-in-orthopyroxene1 thermometry provided T of 1028–1068 °C, and Ca-in-orthopyroxene2 thermometry gave 909–961 °C at estimated P of 1.1–0.9 GPa. However, the gabbroic dyke magmatic crystallization T was constrained to 1200–1100 °C at P of 0.45–0.15 GPa by single clinopyroxene thermobarometry. The obtained P–T conditions constrained the deeper mantle environment for the formation of peridotites than troctolites and crosscutting dykes. The ophiolitic thrust-sheet hanging wall conditions in an obduction-related accretionary wedge were estimated from amphibolites at 620 °C and 0.85 GPa by Ti-in-amphibole thermometry and amphibole-plagioclase thermobarometry. 300 °C and 0.5 GPa were determined from an exhumation shear zone using a combination of chlorite thermometry and Si-in-phengite barometry.
Postorogenic volcanic rocks of different Tertiary ages are very common in the Sava-Vardar Zone of the Dinarides and in the southeastern part of adjoing Pannonian Basin. South of the Sava-Vardar Zone, in central Bosnia, Tertiary volcanic rocks occur within ophiolite sequences and genetically related sedimentary formations of the Dinaride Ophiolite Zone. Central Bosnia volcanic rocks are mostly dacites, and highly subordinately andesites as the members of the high-K calc-alkaline series.It appears from the mineralogical and petrographic characteristics obtained some insight into the processes that occurred during the genesis of the rocks. The presence of primary igneous minerals: clinopyroxene, orthopyroxene, hornblende and biotite from ferromagnesian minerals, and plagioclase, sanidine and quartz, indicates that the fractional crystallization played a significant role in the genesis of the rocks. Reaction edge on many rounded quartz phenocrysts indicates the possibility of magma mixing with the formation of Tertiary volcanic rocks of the central Bosnia. On magma mixing different temperature and chemical composition also indicates the existence of zoned plagioclase and amphibole phenocrysts.Complex compositional and zoning patterns of biotite and plagioclase phenocrysts and disequilibrium microstructures of plagioclase and quartz phenocrysts suggest interaction of fractionating, mantle derived melts with continental crust during a shalow level pre-eruptive stage and mixing with small amount of devolatilized phlogopite-phyric mafic magma before eruption.
SUMMARYTotal number of nineteen mafic extrusive rock samples is subjected to the detailed optical examination. Based on definition of mineral composition, structure, texture, type and intensity of alteration processes, and taking into consideration the recent classification schemes, different lithotypes are defined. The most frequent are spilites distinguished by classical "spilite" mineralogy (albite), and very often with "quench" texture and amygdaloidal structure. Diabases consist of primary plagioclase and clinopyroxene which are often decomposed and disintegrated. Diabase rocks are mostly characterised with ophitic texture and massive structure. Coarse grained varieties are characterized as dolerites, the rocks in which intensity of alteration process is significantly lower than in previous lithotypes. Varieties with frequent occurrences of amphibole got adjective amphibolic. The most common and the most intense alteration processes are albitization and chloritization. Alteration processes of lower intensity are actinolitization, pumpellytization, zeolitization, carbonation-calcitization, limonitization, kaolinitization and silicification. Depending on alteration degree a certain lithotypes are named with prefix meta (metadiabases and metadolerites).
<p>The Ozren ophiolite complex (OOC) is the second largest ophiolite complex in Bosnia and Herzegovina, and it is a part of the huge Dinaride ophiolite belt [1 and reference therein]. This contribution comprises mineralogical-petrographical descriptions of representative rocks of the OOC which were determined from polished sections by polarized light microscopy and introductory EPMA. The investigated harzburgites are composed of Ol (55%), Opx porphyroclasts with Cpx exsolution lamellae (35%), Cpx with Opx exsolution lamellae (5%) the latter following Ol-Opx boundaries or ingrowing Opx and Ol matrix. Spinel occurs in the form of anhedral grains. Lherzolites contain Ol (55%), Opx (25%) and Cpx (15%). Anhedral Opx porphyroclasts have Cpx exsolution lamellae. Similarly, porphyroclastic Cpx contains Opx exsolution lamellae. Late magmatic Cpx and Opx aggregates are ingrowing the Ol matrix and these are also surrounding deformed Opx porphyroclasts. Spinel is immersed in the Ol matrix. Dunites are rare. A remnant of the gabbroic layer is inferred only from a borehole core. This gabbro has ophitic texture and contains primary magmatic porphyric Pl, Cpx and green Amp1. Pyroxene and Amp1 are partially replaced by Amp2 and Chl. Plagioclase is weakly altered. Moreover, we found cross-cutting dykes of gabbros (micro-gabbros, called dolerites, to gabbro-pegmatites, and dunite-associated troctolite) in peridotite. These dykes have randomly oriented minerals, only locally showing mylonitization signatures. Most dykes have a discordant relationship to the peridotite structures. Dolerites and basalts also occur in the form of relatively thicker lens-like bodies in serpentinites. A basaltic dyke cross-cuts layered gabbro (in borehole). Most dolerites are composed of Cpx, Amp and Pl but we also found an exceptional Ol-dolerite dyke cross-cutting peridotite. It has well preserved magmatic ophitic texture composed of Ol, Opx, Cpx, Amp, Pl, Ilm and Ap. Pyroxenes and amphiboles are weakly chloritized and Ol is serpentinized. Dolerites and basalts have an ophitic texture, defined by fine-grained prismatic Pl, Px and Amp. Secondary Amp2 and Chl follow the grain boundaries of magmatic minerals. Ophiolitic breccias cover some peridotite parts. These breccias contain 1cm &#8211; 10m fragments of all lithological sequences of the OOC including reddish radiolarite sediments. Gabbros from ophiolitic breccia have coarse grained Pl and Px. Exsolution lamellae in Px and kink-banding are characteristic features from subsolidus magmatic conditions. A rare plagiogranite intrusion in peridotite is composed of Qz, Pl and needle-like Amp aggregates after Bt. Such an association of ultrabasic and basic rocks may indicate percolating gabbroic magmas through the peridotites. Amphibolites were found only at one locality so far and these are composed of oriented Amp and Pl aggregates in the metamorphic texture, most likely indicating metamorphic sole of an ophiolitic thrust sheet. These preliminary results shed light on the lithology and petrography of the OOC and have arisen problems for further research.</p> <p><strong>References:</strong></p> <p>[1] Babaji&#263; E. (2019) Krivaja-Konjuh ophiolite complex &#8211; petrology, geochemistry and geotectonics of mafic sequences. (Monograph), MIT-ALEX, Tuzla (Bosnia and Herzegovina)</p> <p><strong>Acknowledgement:</strong> APVV Agency Project No. APVV-19-0065 (M.P.) is acknowledged.</p>
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