Forty-two mosaic coloured/opaque "glass" tesserae from three sites (Milan, Italy; Durrës, Albania; Hierapolis, Turkey) situated in the Western and Eastern parts of the Roman/Byzantine Empire, dated between the 5 th and the 9 th centuries, were studied by optical microscopy, SEM-EDX and Raman microspectroscopy in order to investigate the nature of their pigments and opacifiers as well as the microstructure of glass ceramic materials. The Raman signatures of glass matrix and phases dispersed in the soda-lime glassy matrix showed the presence of six opacifiers/pigments. The use of soda ash glass in the tesserae from Durrës (post 8 th c.) allows refining the mosaic debated chronology. The use of soda ash matrix glass together with the presence of calcium antimonates (Ca 2 Sb 2 O 7 and CaSb 2 O 6 ), pyrochlore solid solution/Naples' yellow (PbSb 2-x-y Sn x M y O 7-δ ) and cuprite (Cu 2 O) or metallic copper (Cu°) in many samples show the technological continuity in a Roman tradition. However, the presence of cassiterite (SnO 2 ) and quartz (SiO 2 ) in one sample from the beginning of the 5 th century, diverging from Roman technology, offers a chronological marker to identify newly (not re-used) produced tesserae.
Graphical abstract
HighlightsOpaque/coloured glass mosaic tesserae exhibit a glass ceramics microstructure.The innovative use of cassiterite (SnO 2 ) and quartz (SiO 2 ) in 5 th century tesserae is evidenced.The technological innovations went alongside the continual use of Roman recipes (calcium antimonate and yellow pigments).
NoveltyThe first use of cassiterite and quartz in the beginning of the 5 th c. as well as the use of calcium antimonates after Roman times in the tesserae produced ex novo with mixed glasses were demonstrated.
The trade of glass beads has long been assumed to have been under Islamic dominance during the early centuries following the Arab conquest of the Middle East, judged by the prevalence of Islamic beads in the archaeological contexts from Viking Scandinavia to medieval Morocco. This paper explores the impact of the Byzantine-Slavic transition on the use and by extension trade of glass beads in the Balkans from the seventh to the ninth century CE. A series of 48 glass beads and 4 vessel fragments from two excavated sites in modern day Albania have been analysed morphologically, technologically and chemically by LA-ICP-MS. The seventh-century beads from Lezha have typological parallels among central European assemblages and are made from recycled natron-type glass. The presence of a high lead-iron-natron variant is of particular interest as it potentially reflects a regional production. The ninth-century beads from Komani are made from soda-rich plant ash glass from the eastern Mediterranean and Mesopotamia and correspond to an Islamic typology. The chronological and geographical differences are reflected in the distinctive cobalt sources used for the two groups. While the beads from Lezha are coloured with a cobalt not correlated with any particular element, the cobalt source of the Komani samples is associated with zinc, typical of Islamic glass making. It thus appears that the supply of beads during the seventh century when the Balkans were under Slavic occupation relied on regional production and recycled material, and that a long-distance trade with the eastern Mediterranean was revived following the Byzantine re-conquest of the south-eastern Adriatic in the ninth century. Intriguingly, the Albanian finds confirm the Islamic control of the production and trade of glass beads during this period and highlight the mediatory role of the Byzantine Empire.
Metal leaf (gold, silver or their alloys) glass tesserae began to be used in wall mosaics in the first century AD (the first examples are in Rome) and their use has been uninterrupted up to day. The metal leaf could be obtained from circulating coins, jewellery or refining. According to various techniques that have changed over the centuries, the leaf was hot fixed between two glass layers. From an archaeological point of view, it is interesting to know when and where these tesserae were made, if they were new made or if they were reused tesserae recovered from earlier dismantled mosaics. The determination of the glass composition of the tesserae is not of great help in this connection, for the same kind of glass was used over long periods. Available information is still scanter for glasses produced between the 1st to 8th centuries when the batch of raw materials (a natural soda called natron and a silica-lime sand) was melted in large tank furnaces and chunks of raw glass were transported all over the Mediterranean to be remelted and shaped into manufacts in small pot furnaces. The SEM-EDS analysis is proposed in this study as a useful tool to investigate the composition of both the glass and the gold alloy in leaf tesserae from mosaics of the 1st -9th centuries. The comparison of the composition of the gold leaf of the tesserae with that of circulating gold coins (for which an important analytical data base is available), adds further information to the glass analysis, allowing us to improve the dating of the tesserae and increase the knowledge that may result from scientific analyses. The results demonstrate that good quantitative analyses of the metal leaf can be performed and that metal leaves made of pure gold or goldsilver alloys were used.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.