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The aim of this study was to evaluate the potential of Hancornia speciosa GOMES (mangaba) seeds as a novel matrix for the production of bio-oil. The study was divided into three steps: (i) characterization of the biomass (through elemental analysis (CHN), infrared spectroscopy (FTIR-ATR), thermogravimetry (TG), and determination of biomass composition; (ii) pyrolysis of mangaba seed to obtain the bio-oil; and (iii) characterization of the bio-oil (thermogravimetry and gas chromatography/mass spectrometry-GC/qMS). The TG of the sample showed a mass loss of around 90% in 450°C. In the pyrolysis experiments the variables included temperature (450 and 600°C), sample mass (5 and 11g) and prior heating (with or without), with the best conditions of 600°C, 11g of seeds and prior heating of the furnace. The GC/qMS analysis identified carboxylic acids and hydrocarbons as the major components, besides the presence of other compounds such as furanes, phenols, nitriles, aldehydes, ketones, and amides.

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The modification of MCM-41 was performed with 3-aminopropropyltrimethoxysilane. The structural order and textural properties of the synthesized materials were studied by X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetry/differential thermogravimetry, nitrogen adsorption, and desorption analysis. The adsorption capacity of NH2-MCM-41 was studied with Remazol Red dye. The following parameters were studied in the adsorption process: pH, temperature, adsorbent dosage, and initial concentration. The desorption process was studied in different concentrations of NaOH solutions. The Freundlich isotherm model was found to be fit with the equilibrium isotherm data. Kinetics of adsorption follows the modified Avrami rate equation. The maximum adsorption capacity was estimated to be 45.9 mg g(-1), with removal of the dye of 99.1%. The NH2-MCM-41 material exhibited high desorption capacity with 98.1%.

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