The ability of urea formaldehyde (UF) resins to develop cold tack is needed in plywood production during pre-pressing in a cold press to ensure that the veneers stick together, can be transported, and fit into a multi-daylight hot press. The influence of defined factors on the cold tack was analyzed by determining the tensile shear strength of uncured birch veneers bonded with UF resin, and the statistically significant impact factors were determined. The factors tested were lay-up time, resin amount, resin age, moisture content, veneer temperature and pre-press time. Moisture content and veneer temperature had the highest impact on the cold tack of UF resins. A negative impact of high moisture content on the tensile shear strength and therefore on the cold tack of UF resins was proven as well as a positive impact of a comparably high (30 °C) veneer temperature. Lay-up time and pre-press time showed a minor impact on the tensile shear strength. Models were created using Design-Expert software to calculate the optimum operation conditions for cold tack.
Subject to this study is the modification of an experimental two-component polyurethane (2C PUR) as an alternative adhesive for structural hardwood bonding. The 2C PUR has been adapted by calcium carbonate as filler to increase its modulus of elasticity with the aim of increasing the modulus analogue to the ones typically observed for classic amino- and phenol based adhesives. The 2C PUR system was compared with a commercial one-component polyurethane (1C PUR) and a phenol resorcinol formaldehyde (PRF) adhesive. The wetting properties of the adhesives were tested in terms of surface tension, polar and dispersive part and contact angle on European beech wood (Fagus sylvatica L.). In addition, adhesive polymer films of 2C PUR were tested for tensile strength and modulus of elasticity (E-Modulus) following ISO 527-1. The adhesives bond performance on beech wood was determined by lap-joints according to EN 302-1 in various climate conditions. The results show that 2C PUR has proper wettability properties on beech wood. Adding 60% wt filler to the polyol component increased the E-Modulus from 2.3 GPa (0%) to 4.4 GPa. The tensile strength of the modified 2C PUR polymer films was comparable with the industrial 1C PUR. Tensile shear strength and wood failure percentage of 2C PUR lap-joints were increased by adding filler and met requirements in dry and re-dried conditions according to EN 302-1. However, the addition of filler didn’t result in an improvement in wet conditions. The present study shows sufficient performance for bonding hardwood with 2C PUR in dry conditions, while the system still needs to be improvement regarding its performance in humid conditions.
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