The aim of this study was to prepare the silver nanoparticles (AgNPs) via chemical reduction and analyze the impact of used reduction agents: sodium borohydride (NaBH4), trisodium citrate (TSC), polyvinylpyrrolidone (PVP), and hydrogen peroxide (H2O2) on the reduction rate of Ag+ ions to Ag0, and on nanoparticles shape. It was proven that combinations of reduction agents dramatically influence the synthesis rate of AgNPs and the color of solutions, which depends on the shape and size of nanoparticles. NaBH4, TSC, and PVP showed good reduction power. In particular, TSC proved to be a key factor influencing the shape of AgNPs. The shape of nanoparticles influences the color of colloidal solutions. Yellow solutions, where UV-vis absorbance maxima (ABSmax) are in the wavelength interval 380–420 nm, contain spherical particles with a mean size of 25 nm, whereas the blue shift of ABSmax to wavelengths higher than 750 nm indicate the presence of triangular nanoparticles (size interval 18–150 nm). A mixture of spherical, triangular, irregular, and hexagonal nanoparticles give different color, e.g., green. The formation and stability of AgNPs was tracked by UV-vis spectroscopy, size and shape by TEM techniques, and particle size distribution was studied by particle size analyzer.
The main causes of the damage of a compressor’s turbine blade are documented and described in the article. The turbine blade was made from titanium alloy grade 5 (VT6, Ti-6Al-4V). The analysed segments of the turbine blade were damaged by corrosion and erosion. The sample from the damaged blade was compared with an undamaged reference sample. The observed substantial distinctions between microstructure of the damaged and the reference sample were found using of light and scanning electron microscopy. The observed distinctions of the microstructure were caused by the differences in the heat treatment process.
This paper analyses a failure of the micro alloyed steel (Re= 500MPa) at a temperature range 400 - 500 oC in the tensile test conditions and in the creep conditions. The failure character in condition tensile test was changeless and the fraction was transcrystalline ductile. The structure near a fraction showed a considerable deformation texture (reduction of area = 76%). The contraction and the fraction stress considerable was decreased by the increase of the time up to the fraction and the by the increase of temperature in the creep conditions. There were formed secondary intercrystalline cracks except the central crack in the area fraction. Intercrystalline cracks were started step by step to be connected each other. The fraction was started to obtain a mixed status alike and the intercrystalline (creep) fraction part was started to increase.
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