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Abstract. Alkenone signatures preserved in marine sedimentary records are considered one of the most robust paleothermometers available and are often used as a proxy for paleoproductivity. However, important gaps remain regarding the provenance and fate of alkenones, as well as their impact on derived environmental signals in marine sediments. Here, we analyze the abundance, distribution and radiocarbon (14C) age of alkenones in bulk sediments and corresponding grain-size fractions in surficial sediments from seven continental margin settings in the Pacific and Atlantic oceans to evaluate the impact of organo-mineral associations and hydrodynamic sorting on sedimentary alkenone signals. We find that alkenones preferentially reside within fine-grained mineral fractions of continental margin sediments, with the preponderance of alkenones residing within the fine-silt fraction (2–10 µm) and most strongly influencing alkenone-14C age and sea surface temperature (SST) signals from bulk sediments as a consequence of their proportional abundance and higher degree of organic matter protection relative to other fractions. Our results provide further evidence for the key role of selective association of alkenones with mineral surfaces and associated hydrodynamic mineral sorting processes on the reliability of alkenone signals encoded in marine sediments (14C age, content and distribution) and the fidelity of corresponding proxy records (productivity and sea SST) in the spatial and temporal domain.

Abstract. Alluvial fan and terrace formation is traditionally interpreted as a fluvial system response to Quaternary climate oscillations under the backdrop of slow and steady tectonic activity. However, several recent studies challenge this conventional wisdom, showing that such landforms can evolve rapidly as a geomorphic system responds to catastrophic and stochastic events, like large-magnitude mass wasting. Here, we contribute to this topic through a detailed field, geochronological, and numerical modelling investigation of thick (>50 m) alluvial sequences in the Klados catchment in southwestern Crete, Greece. The Klados River catchment lies in a Mediterranean climate, is largely floored by carbonate bedrock, and is characterised by well-preserved alluvial terraces and inset fans at the river mouth that exceed the volumes of alluvial deposits in neighbouring catchments of similar size. Previous studies interpreted the genesis and evolution of these deposits to result from a combination of Pleistocene sea-level variation and the region's long-term tectonic activity. We show that the >20 m thick lower fan unit, previously thought to be late Pleistocene in age, unconformably buries a paleoshoreline uplifted in the first centuries CE, placing the depositional age of this unit firmly in the late Holocene. The depositional timing is supported by seven new radiocarbon dates that indicate middle to late Holocene ages for the entire fan and terrace sequence. Furthermore, we report new evidence of a previously unidentified valley-filling landslide deposit that is locally 100 m above the modern stream elevation, and based on cross-cutting relationships, it predates the alluvial sequence. Observations indicate the highly erodible landslide deposit as the source of the alluvial fill sediment. We identify the likely landslide detachment area as a large rockfall scar at the steepened head of the catchment. A landslide volume of 9.08×107 m3 is estimated based on volume reconstructions of the mapped landslide deposit and the inferred scar location. We utilise landslide runout modelling to validate the hypothesis that a high-magnitude rockfall would pulverise and send material downstream, filling the valley up to ∼100 m. This partial liquefaction is required for the rockfall to form a landslide body of the extent observed in the valley and is consistent with the sedimentological characteristics of the landslide deposit. Based on the new age control and the identification of the landslide deposit, we hypothesise that the rapid post-landslide aggradation and incision cycles of the alluvial deposits are not linked to long-term tectonic uplift or climate variations but rather stochastic events such as mobilisation of sediment in large earthquakes, storm events, or ephemeral blockage in the valley's narrow reaches. The Klados case study represents a model environment for how stochastically driven events can mimic climate-induced sedimentary archives and lead to deposition of thick alluvial sequences within hundreds to thousands of years, and it illustrates the ultrasensitivity of mountainous catchments to external perturbations after catastrophic events.

Abstract. Alluvial fan and terrace formation is traditionally interpreted as related to Quaternary climate oscillations under the backdrop of slow and steady tectonic activity. However, several recent studies challenge this conventional wisdom, showing that such landforms can evolve rapidly as a geomorphic system responds to catastrophic and stochastic events, like large magnitude mass-wasting. Here, we contribute to this topic through a detailed field and geochronological investigation of alluvial sequences in the Klados catchment in southwestern Crete, Greece. The Klados River catchment is characterised by well-preserved, alluvial terraces and a set of fans at the river mouth, which do not seem to fit the sediment capacity of a small catchment with a drainage area of ~ 11.5 km2. Previous studies interpreted the formation of the deposits and their development to be of Pleistocene age and controlled by climate variations and the region's long-term tectonic activity. We find that the > 20 m thick intermediate fan buries a paleoshoreline uplifted in AD 365 placing the depositional age of this unit firmly into the Late Holocene. This is supported by seven new radiocarbon dates that infer mid to late Holocene ages for the entire fan and terrace sequence. As sediment source, we identify a landslide scar at the head of the catchment. We document landslide deposits 100 m above the modern stream and utilise landslide runout modelling to reconstruct landslide volumes and validate our hypothesis. We find that a landslide volume of 0.0908 km2 matches the observed distribution of landslide deposits and the landslide scar dimensions. We hypothesise that subsequent aggradation and incision cycles of the alluvial deposits are not linked to long-term tectonic uplift and climate variations but rather stochastic events such as mobilisation of sediment in large earthquakes, storm events, or blockage in the valley's narrow reaches. The Klados case study represents a model-environment for how stochastically-driven events can mimic climate-induced sedimentary archives, and how catchments can become ultrasensitive to external perturbations after catastrophic events.

Continental margin sediments represent a major global sink of organic carbon (OC), and as such exert a key control on Earth’s climate. Today, OC burial in marine sediments mainly takes place under oxygen-rich water columns, where most OC is stabilized through intimate association with sediment grains and biogenic minerals. In prior episodes of Earth’s past, when large parts of the oceans were anoxic, the mode of sedimentary OC burial must have been very different, however. Present-day analogues indicate that surface sediments accumulating under low-oxygen water columns are often “soupy” in texture. Moreover, most OC occurs in large (100–2,000 μm diameter) organic and organo-mineral aggregates which, due to their low density, are prone to wave- and current-induced resuspension. Upon mobilization, these aggregates can undergo lateral transport within so-called nepheloid layers, and may be translocated hundreds of kilometres, and on timescales of thousands of years. Little is known about processes of formation, resuspension and hydrodynamic properties of these aggregates in oxygen-poor waters, or which factors control their eventual breakdown or burial. The goal of this study is to examine the drivers and biogeochemical consequences of this resuspension on OC cycling in modern, oxygen-depleted, “Semi-Liquid Ocean Bottom” (SLOB) regions. We argue that models of sediment and OM hydrodynamics and redistribution that describe sedimentation processes in oxygenated ocean waters of the modern ocean are a poor analogue for equivalent processes occurring under oxygen-deficient conditions. In the latter, we hypothesize that 1) the abundance of low-density organic-rich particles and aggregates leads to a greater propensity for sediment remobilization at low(er) shear stress, and 2) upon resuspension into low-oxygen bottom waters, remobilized OM may be subject to less degradation (less attenuation) during lateral transport, leading to efficient and widespread translocation to distal centres of deposition. We address specific aspects of the SLOB hypothesis utilizing a combination of literature and new data, focussing on the Benguela Upwelling Region as a model system.