Transition Metal Complexes with Charge-Compensated Dicarbollide Ligands -[110 refs. + subrefs.]. -(TIMOFEEV, S. V.; SIVAEV, I. B.; PRIKAZNOVA, E. A.; BREGADZE*, V. I.; J. Organomet. Chem. 751 (2014) 221-250, http://dx.
Charge-compensated mono- and bidentate nido-carboranyl thioether ligands [7-MeS-9-Me3N-7,8-C2B9H10], [7-MeS-11-Me3N-7,8-C2B9H10] and [7,8-(MeS)2-9-Me3N-7,8-C2B9H9] were synthesized. They readily react with labile tungsten carbonyl complex W(CO)5(THF) to give the corresponding σ-complexes (CO)5W[7-MeS-9-Me3N-7,8-C2B9H10-κ1-S(7)], (CO)5W[7-MeS-11-Me3N-7,8-C2B9H10-κ1-S(7)] and...
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