The
equilibrium structure of supramolecular magnetic filament brushes
is analyzed at two different scales. First, we study the density and
height distributions for brushes with various grafting densities and
chain lengths. We use Langevin dynamics simulations with a bead–spring
model that takes into account the cross-links between the surface
of the ferromagnetic particles, whose magnetization is characterized
by a point dipole. Magnetic filament brushes are shown to be more
compact near the substrate than nonmagnetic ones, with a bimodal height
distribution for large grafting densities. This latter feature makes
them also different from brushes with electric dipoles. Next, in order
to explain the observed behavior at the filament scale, we introduce
a graph theory analysis to elucidate for the first time the structure
of the brush at the scale of individual beads. It turns out that,
in contrast to nonmagnetic brushes, in which the internal structure
is determined by random density fluctuations, magnetic forces introduce
a certain order in the system. Because of their highly directional
nature, magnetic dipolar interactions prevent some of the random connections
to be formed. On the other hand, they favor a higher connectivity
of the chains’ free and grafted ends. We show that this complex
dipolar brush microstructure has a strong impact on the magnetic response
of the brush, as any weak applied field has to compete with the dipole–dipole
interactions within the crowded environment.
We present a theoretical study of Janus-like magnetic particles at low temperature. To describe the basic features of the Janus-type magnetic colloids, we put forward a simple model of a spherical particle with a dipole moment shifted outwards from the centre and oriented perpendicular to the particle radius. Using direct calculations and molecular dynamics computer simulations, we investigate the ground states of small clusters and the behaviour of bigger systems at low temperature. In both cases the important parameter is the dipolar shift, which leads to different ground states and, as a consequence, to a different microscopic behaviour in the situation when the thermal fluctuations are finite. We show that the head-to-tail orientation of dipoles provides a two-particle energy minima only if the dipoles are not shifted from the particle centres. This is one of the key differences from the system of shifted dipolar particles (sd-particles), in which the dipole was shifted outwards radially, studied earlier (Kantorovich et al 2011 Soft Matter 7 5217-27). For sd-particles the dipole could be shifted out of the centre for almost 40% before the head-to-tail orientation was losing its energetic advantage. This peculiarity manifests itself in the topology of the small clusters in the ground state and in the response of the Janus-like particle systems to an external magnetic field at finite temperatures.
We present a theoretical study on the design of a supramolecular magnetoresponsive coating. The coating is formed by a relatively dense array of supracolloidal magnetic filaments grafted to a surface in a polymer brush-like arrangement. In order to determine and optimise the properties of the magnetic filament brush, we perform extensive computer simulations with a coarse-grained model that takes into account the correlations between the magnetic moments of the particles and the backbone crosslinks. We show that the self-assembly of magnetic beads from neighbouring filaments defines the equilibrium structural properties of the complete brush. In order to control this self-assembly, we highlight two external stimuli that can lead to significant effects: temperature of the system and an externally applied magnetic field. Our study reveals self-assembly scenarios inherently driven by the crosslinking and grafting constraints. Finally, we explain the mechanisms of structural changeovers in the magnetic filament brushes and confirm the possibility of controlling them by changing the temperature or the intensity of an external magnetic field.
This paper presents a homogeneous system of magnetic colloidal particles that self-assembles via two structural patterns of different symmetry. Based on a qualitative comparison between a real magnetic particles system, analytical calculations and molecular dynamics simulations, it is shown that bistability can be achieved by a proper tailoring of an anisotropic magnetization distribution inside the particles. The presented bistability opens new possibilities to form two-dimensionally extended and flexible structures where the connectivity between the particles can be changed in vivo.
We study the self-assembly of colloidal magnetic particles permanently cross-linked into polymer-like structures with different topologies, that we call supracolloidal magnetic polymers (SMPs). In order to understand the influence of the interparticle permanent links, we investigate SMPs holding the main topologies observed in the self-assembly of non-cross-linked magnetic particles via grand canonical Monte Carlo simulations: chains, rings and simple branched structures. Here, using molecular dynamics simulations, we focus on systems of SMP pairs. Our results evidence that the presence of crosslinkers leads to the formation of new types of aggregates, not previously observed for individual magnetic colloids.
ARTICLE HISTORY
In the present manuscript we develop a theoretical approach to describe the pair correlation function of bidisperse magnetic dipolar hard- and soft-spheres. We choose bidisperse system as the first step to allow for polydispersity when studying thermodynamics of magnetic fluids. Using diagram technique we calculate the virial expansion of the pair correlation function up to the first order in density and fourth order in the dipolar strength. Even though, the radial distribution functions are extremely sensitive to the steric potential, we show that the behaviour of the isotropic centre-centre structure factor is almost indifferent to the type of the short-range repulsion. We extensively compare our theoretical results to the data of molecular dynamics simulations, which helps us to understand the range of validity of the virial expansion both on density and magnetic dipolar strength. We also investigate the influence of the granulometric composition on the height, width, and position of the structure factor first peak in order to clarify whether it is possible to extract structural information from experimentally measured small angle neutron scattering intensities.
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