Spontaneous light emission is known to be affected by the local density of states and enhanced when coupled to a resonant cavity. Here, we report on an experimental study of siliconvacancy (SiV) color center fluorescence and spontaneous Raman scattering from subwavelength diamond particles supporting loworder Mie resonances in the visible range. For the first time to our knowledge, we have measured the size dependences of the SiV fluorescence emission rate and the Raman scattering intensity from individual diamond particles in the range from 200 to 450 nm. The obtained dependences reveal a sequence of peaks, which we explicitly associate with specific multipole resonances. The results are in agreement with our theoretical analysis and highlight the potential of intrinsic optical resonances for developing nanodiamond-based lasers and single-photon sources.
Over the past two decades, nanosized diamond particles with various luminescent defects have found numerous applications in many areas from quantum technologies to medical science. The size and shape of diamond particles can affect drastically the luminescence of embedded color centers. Here we study diamond particles of 250–450 nm in size containing silicon-vacancy (SiV) centers. Using dark-field scattering spectroscopy, we found that fundamental Mie resonances are excited in the spectral range of interest. We then measured the fluorescence saturation curves under continuous excitation to estimate the effects of the excitation and Purcell factor enhancement on the luminescent properties of the studied particles. The results show that the saturation excitation intensity differs by several times for particles of different sizes which is well explained by the numerical model that takes into account both the Parcell factor enhancement and resonant excitation.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.