A B S T R A C TThis study is focused on oxidative degradation of Methyl Orange, a common azo dye, catalyzed by nickel hydroxide in aqueous solution at 303, 313, 323, and 333 K. Sodium hypochlorite, sodium hydroxide, and nickel sulfate hexahydrate in distilled water were used as starting material for preparation of nickel hydroxide. Pyrex glass batch reactor was used to study the effect of various conditions such as temperature, concentration, agitation, and catalyst dose on catalytic degradation of Methyl Orange in aqueous medium. About 80% Methyl Orange was degraded in 120 min. Experimental data were subjected to kinetic analysis using CurveExpert software. Degradation reaction was taking place according to Langmuir-Hinshelwood mechanism. According to this mechanism, the reactants adsorb at the surface of catalyst in first step followed by reaction between adsorbed reactants in second step. Adsorption of Methyl Orange on surface of catalyst followed Langmuir adsorption isotherm. Apparent activation energy, true activation energy, and heat of adsorption were determined as 13.2, 32.7 and -23.5 kJ mol −1 , respectively.
Reddit consists of sub-communities that cover a focused topic. This paper provides a list of relevant subreddits for the ongoing Russo-Ukrainian crisis. We perform an exhaustive subreddit exploration using keyword search and shortlist 12 subreddits as potential candidates that contain nominal discourse related to the crisis. These subreddits contain over 300,000 posts and 8 million comments collectively. We provide an additional categorization of content into two categories, "R-U Conflict", and "Military Related", based on their primary focus. We further perform content characterization of those subreddits. The results show a surge of posts and comments soon after Russia launched the invasion. "Military Related" posts are more likely to receive more replies than "R-U Conflict" posts. Our textual analysis shows an apparent preference for the Pro-Ukraine stance in "R-U Conflict", while "Military Related" retain a neutral stance.
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