The novel poly(vinyl alcohol) (PVA)-based membranes were prepared using the two-step crosslinking approach: the chemical crosslinking of PVA using sulfosuccinic acid (SSA) (0–50 wt.%) and the thermal treatment (120–160 °C). The membrane composition and crosslinking temperature were optimized in terms of the mechanical and transport properties. The FTIR-ATR analysis revealed that the increase of the SSA concentration and crosslinking temperature resulted in the rise of the ester bond bands intensity due to the esterification reaction between PVA and SSA. As a consequence, the PVA-based membrane with 50 wt % SSA and crosslinked at 140 °C showed the reduced Young’s modulus (from 1266.2 MPa to 1.4 MPa) and elongation at break (from 316% to 66%) in comparison with the pure PVA membrane. The studied swelling behavior of the obtained membranes revealed significantly higher water sorption than that in methanol and propal-2-ol whatever the crosslinking temperature. The performed studies provide a new way of tailoring the membrane physicochemical properties, in particular, the surface hydrophilicity. In addition, the obtained results are crucial for the design and elaboration of the polymer membranes for the pervaporative separation of the liquid-liquid mixtures, in particular, for the alcohol dehydration.

Abstract The interest in ionic liquids, particularly in polymerizable ionic liquids, is motivated by their unique properties, such as good thermal stability, negligible vapor pressure, and wide electrochemical window. Due to these features ionic liquids were proposed to be used in the membrane separation technology. The utilization of conventional ionic liquids is, however, limited by their release from the membrane during the given separation process. Therefore, the incorporation of polymerizable ionic liquids may overcome this drawback for the industrial application. This work is a comprehensive overview of the advances of ionic liquid membranes for the separation of various compounds, i.e. gases, organic compounds, and metal ions.

The high-temperature proton exchange membrane fuel cell (HT-PEMFC) offers several advantages, such as high proton conductivity, high CO tolerance, good chemical/thermal stability, good mechanical properties, and low cost. The proton exchange membrane (PEM) is the critical component of HT-PEMFC. This work discusses the methods of current PEMs development for HT-PEMFC including modifications of Nafion® membranes and the advancement in composite PEMs based on non-fluorinated polymers. The modified Nafion®-based membranes can be used at temperatures up to 140 °C. Nevertheless, the application of Nafion®-based membranes is limited by their humidification with water molecules acting as proton carriers and, thus, by the operation conditions of membranes under a relative humidity below 20%. To obtain PEMs applied at higher temperatures under non-humidified conditions, phosphoric acid (PA) or ionic liquids (ILs) are used as proton carriers in PEMs based on non-fluorinated polymers. The research discussed in this work provides the approaches to improving the physicochemical properties and performance fuel cell of PEMs. The effects of polymer blending, crosslinking, and the incorporation of inorganic particles on the membrane properties and fuel cell performance have been scrutinized. The incorporation of inorganic particles modified with ILs might be an effective approach to designing high-performance PEMs for HT-PEMFC.

Pervaporation is a membrane-separation technique which uses polymeric and/or ceramic membranes.In the case of pervaporation processes applied to dehydration, the membrane should transport water molecules preferentially. Reactive ionic liquid (RIL) (3-(1,3-diethoxy-1,3-dioxopropan-2-yl)-1-methyl-1H-imidazol-3-ium) was used to prepare novel dense cellulose acetate propionate (CAP) based membranes, applying the phase-inversion method. The designed polymer-ionic liquid system contained ionic liquid partially linked to the polymeric structure via the transesterification reaction. The various physicochemical, mechanical, equilibrium and transport properties of CAP-RIL membranes were determined and compared with the properties of CAP membranes modified with plasticizers, i.e., tributyl citrate (TBC) and acetyl tributyl citrate (ATBC). Thermogravimetric analysis (TGA) testified that CAP-RIL membranes as well as CAP membranes modified with TBC and ATBC are thermally stable up to at least 120 • C. Tensile tests of the membranes revealed improved mechanical properties reflected by reduced brittleness and increased elongation at break achieved for CAP-RIL membranes in contrast to pristine CAP membranes. RIL plasticizes the CAP matrix, and CAP-RIL membranes possess preferable mechanical properties in comparison to membranes with other plasticizers investigated. The incorporation of RIL into CAP membranes tuned the surface properties of the membranes, enhancing their hydrophilic character. Moreover, the addition of RIL into CAP resulted in an excellent improvement of the separation factor, in comparison to pristine CAP membranes, in pervaporation dehydration of propan-2-ol. The separation factor β increased from ca. 10 for pristine CAP membrane to ca. 380 for CAP-16.7-RIL membranes contacting an azeotropic composition of water-propan-2-ol mixture (i.e., 12 wt % water).

The work is devoted to a computational study of three types of cationic polymeric membranes in Li + -ionic form, in water and methanol environments, at various solvation levels. The studied membranes Nafion, IonClad, and M3 possess the perfluorinated backbone; however, various side chains were terminated with the functional groups of distinctly different ionic strength. The paper discusses the structural features of the membrane-solvent clusters as well as an influence of the side chain nature on the dissociation of the functional groups and the binding energy of the solvent molecules. Additionally, the paper compares the obtained results for Li + -Nafion membrane in water with the results published earlier for H + and Na + forms.

1-(1,3-diethoxy-1,3-dioxopropan-2-ylo)-3-methylimidazolium bromide (RIL1_Br), 1-(2-etoxy-2-oxoethyl)-3-methylimidazolium bromide (RIL2_Br), 1-(2-etoxy-2-oxoethyl)-3-methylimidazolium tetrafluoroborate (RIL3_BF4) ionic liquids were synthesized. Subsequently, the dense cellulose acetate propionate (CAP)-based materials containing from 9 to 28.6 wt % of these reactive ionic liquids were elaborated. Reactive ionic liquids (RILs) were immobilized in CAP as a result of the transesterification reaction. The yield of this reaction was over 90% with respect to the used RIL. The physicochemical properties of resultant films were studied using nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), atomic force microscopy (AFM), and thermogravimetric analysis (TGA). The RIL incorporation influenced the morphology of films by increasing their surface roughness with the rise of RIL content. The thermal stability of CAP-based membranes was dependent on the nature of the ionic liquid. Nevertheless, it was proven that CAP films containing RILs were stable up to 120–150 °C. Transport properties were characterized by water permeation tests. It was found that the type and the amount of the ionic liquid in the CAP matrix substantially influenced the transport properties of the prepared hybrid materials.

No abstract

No abstract