We report on the dynamical properties of interacting colloids confined to one dimension and subjected to external periodic energy landscapes. We particularly focus on the influence of hydrodynamic interactions on the mean-square displacement. Using Brownian dynamics simulations, we study colloidal systems with two types of repulsive interparticle interactions, namely, Yukawa and superparamagnetic potentials. We find that in the homogeneous case, hydrodynamic interactions lead to an enhancement of the particle mobility and the mean-square displacement at long times scales as t(α), with α=1/2+ε and ε being a small correction. This correction, however, becomes much more important in the presence of an external field, which breaks the homogeneity of the particle distribution along the line and, therefore, promotes a richer dynamical scenario due to the hydrodynamical coupling among particles. We provide here the complete dynamical scenario in terms of the external potential parameters: amplitude and commensurability.

We report on the hydrodynamic correlations between colloids immersed in a low Reynolds number fluid. We consider colloidal arrays composed of three particles; each colloid is trapped in a single harmonic potential and interacts with the other colloids only via hydrodynamic forces. We focus on the role of a third body in the two-body correlation functions. We give special attention to a collinear configuration of particles, although the salient features of an equilateral triangle configuration are outlined. The correlation functions are computed both by means of Brownian dynamics simulations, and by solving analytically and numerically the Langevin equation under the assumption of constant diffusion tensor; this approximation is validated through computer simulations. We explicitly show that the presence of a third body affects the auto- and cross-correlation functions and that their behaviour, in some specific conditions, can be different from that commonly seen in a two-particle system. In particular, we have found that the auto-correlation functions show a slower decay, while the cross-correlation ones exhibit a temporal shift and a weaker amplitude. Moreover, an unexpected behaviour related to a positive correlation and associated with the appearance of new dynamical modes is observed in the case of the collinear array of three particles. This interesting effect might be used to tune the degree of hydrodynamic correlation in few-body colloidal systems.

We report on the ordering and dynamics of interacting colloidal particles confined by a parabolic potential. By means of Brownian dynamics simulations, we find that by varying the magnitude of the trap stiffness, it is possible to control the dimension of the system and, thus, explore both the structural transitions and the long-time self-diffusion coefficient as a function of the degree of confinement. We particularly study the structural ordering in the directions perpendicular and parallel to the confinement. Further analysis of the local distribution of the first-neighbors layer allows us to identify the different structural phases induced by the parabolic potential. These results are summarized in a structural state diagram that describes the way in which the colloidal suspension undergoes a structural re-ordering while increasing the confinement. To fully understand the particle dynamics, we take into account hydrodynamic interactions between colloids; the parabolic potential constricts the available space for the colloids, but it does not act on the solvent. Our findings show a non-linear behavior of the long-time self-diffusion coefficient that is associated to the structural transitions induced by the external field.

The dynamical properties of interacting colloids spatially restricted to move in one-dimensional channels [J. Chem. Phys. 133, 114902 (2010)] and subjected to external periodic energy landscapes [Phys. Rev. E 86, 081123 (2012)] have been recently reported in terms of the long-time self-diffusion behavior. However, the full description of the mean-square displacement, ranging from short times to long times, is still missing. Thus, by means of Brownian dynamics computer simulations, we revisit the process known as single-file diffusion in driven interacting colloidal systems at all time scales. In particular, we review three different pair potentials, namely, Weeks–Chandler–Andersen, Yukawa and superparamagnetic potentials. We mainly focus on the importance of the correlation between particles via the coupling among hydrodynamic interactions and the external periodic field, resulting in nontrivial particle dynamics along the file in systems composed of repulsively interacting particles. [Formula: see text] Special Issue Comments: This article reviews results on the dynamical properties of interacting colloids in a single file when they are subjected to external periodic energy landscapes presented before in [J. Chem. Phys. 33, 114902 (2010)] and [ Phys. Rev. E 86, 081123 (2012)]. We analyze different interactions that cover from short to long ranges of the interparticle potentials. We mainly focus on the importance of the correlation between particles via the coupling among the hydrodynamic interactions and the external periodic field. Note from Publisher: In the captions of Figs. 1 through 4, "??" has appeared where the number 9 should appear. In table 1, in the WCA section, the variable "φ" shows the values: 0.2,0.3,0.3,0.3,0.3,0.3. The correct values are: 0.2, 0.3, 0.4, 0.5 , 0.6 , 0.7.

No abstract

Confinement can induce substantial changes in the physical properties of macromolecules in suspension. Soft confinement is a particular class of restriction where the boundaries that constraint the particles in a region of the space are not well-defined. This scenario leads to a broader structural and dynamical behavior than observed in systems enclosed between rigid walls. In this contribution, we study the ordering and diffusive properties of a two-dimensional colloidal model system subjected to a one-dimensional parabolic trap. Increasing the trap strength makes it possible to go through weak to strong confinement, allowing a dimensional transition from two- to one-dimension. The non-monotonic response of the static and dynamical properties to the gradual dimensionality change affects the system phase behavior. We find that the particle dynamics are connected to the structural transitions induced by the parabolic trap. In particular, at low and intermediate confinement regimes, complex structural and dynamical scenarios arise, where the softness of the external potential induces melting and freezing, resulting in faster and slower particle diffusion, respectively. Besides, at strong confinements, colloids move basically along one direction, and the whole system behaves structurally and dynamically similar to a one-dimensional colloidal system.

Confinement can induce substantial changes in the physical properties of macromolecules in suspension. Soft confinement is a particular class of restriction where the boundaries that constraint the particles in a region of the space are not well-defined. This scenario leads to a broader structural and dynamical behavior than the observed in systems enclosed between rigid walls. In this contribution, we study the ordering and diffusive properties of a two-dimensional colloidal model system subjected to a one-dimensional parabolic trap. Increasing the trap strength makes it possible to go through weak to strong confinement, allowing a dimensional transition from two- to one-dimension. The non-monotonic response of the static and dynamical properties to the gradual dimensionality change affects the system phase behavior. We find that the particle dynamics is connected with the structural transitions induced by the parabolic trap. In particular, at low and intermediate confinement regimes, complex structural and dynamical scenarios arise, where the softness of the external potential induces melting and freezing, resulting in faster and slower particle diffusion, respectively. Besides, at strong confinements, colloids move basically along one direction, and the whole system behaves structurally and dynamically similar to a one-dimensional colloidal system.