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Magnetic Barkhausen noise (MBN) was used to characterize the progress of austenite to martensite phase transformation while cooling steel specimens, using a conventional Barkhausen noise emission setup stimulated by an alternating magnetic field. The phase transformation was also followed by electrical resistivity measurements and by optical and scanning electron microscopy. MBN measurements on a AISI D2 tool steel austenitized at 1473 K and cooled to liquid nitrogen temperature presented a clear change near 225 K during cooling, corresponding to the MS (martensite start) temperature, as confirmed by resistivity measurements. Analysis of the resulting signals suggested a novel experimental technique that measures spontaneous magnetic emission during transformation, in the absence of any external field. Spontaneous magnetic noise emission measurements were registered in situ while cooling an initially austenitic sample in liquid nitrogen, showing that local microstructural changes, corresponding to an avalanche or “burst” phenomena, could be detected. This spontaneous magnetic emission (SME) can thus be considered a new experimental tool for the study of martensite transformations in ferrous alloys, at the same level as acoustic emission.

In this work, a SiO2-TiO2 coating, composed of different numbers of TiO2 and SiO2 layers, was fabricated by a spray-coating technique. The films were deposited onto ignimbrite rock and divided into two groups according to the number of SiO2 layers applied, 10 and 15 layers of SiO2 and 5 layers of TiO2 for each group. The morphology and chemical composition of the synthesized samples were characterized by field emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray spectrometer (EDS), which reveal the successful SiO2-TiO2 coating on ignimbrite. The photocatalytic activities of samples obtained were evaluated toward the decomposition of 3 ppm of methyl orange (MO). Finally, NOx gas degradation was studied. The obtained results evidenced that the SiO2 and TiO2 coating improved the photocatalytic activity of ignimbrite.

Duplex stainless steels have a structure normally composed of austenite and ferrite in approximately equal proportions. In order to attain control of its fabrication processes and performance, it is important to understand its microstructural evolution, due to the formation of intermetallic phases such as sigma (σ) and chi (χ), which may cause a severe deterioration of mechanical properties. In the present study, the evolution of sigma phase during heat treatments at temperatures in which intermetallic phases can be formed (800ºC-900°C) was studied using magnetic analyses on a SAF2205 (DIN 1.4462/UNS S31803) steel. A significant reduction of the intensity of Magnetic Barkhausen Noise (MBN) was observed with the increase of heat treatment time, indicating a decrease in the quantity of ferromagnetic phases. For 24-hour-long treatments, the Barkhausen Noise signal is almost completely enclosed by the background noise, indicating the existence of a very small volume fraction of ferrite. If proper calibration samples are to be produced, this technique may be a viable method for non-destructive evaluation of field components working under thermal conditions that may cause the formation of intermetallic phases.

ResumoOs aços inoxidáveis duplex (AID), apresentam em geral uma microestrutura composta de austenita e ferrita em proporções aproximadamente iguais. Para ter o controle dos processos de fabricação e desempenho é importante conhecer sua evolução microestrutural, devido à precipitação de fases intermetálicas como sigma (σ) e chi (χ), que causam grave deterioração das propriedades mecânicas do material. Neste trabalho foi estudada a evolução da fase sigma (σ) durante tratamentos térmicos em temperaturas intermetálicas (800°C-900°C) de amostras do aço inoxidável duplex tipo SAF2205 (DIN 1.4462/UNS 31803). Foi observada uma gradual redução da intensidade do sinal do ruído de Barkhausen com o aumento do tempo de tratamento térmico, indicando uma redução na fração de fase ferromagnética. Para tempos de tratamento de 24 horas, o sinal de Ruído de Barkhausen está quase totalmente inserido dentro do ruído de fundo da medida, indicando haver uma fração volumétrica bastante reduzida de ferrita. Por meio da produção de amostras padrão para calibração, essa pode ser uma via de avaliação não destrutiva de componentes submetidos em campo a temperaturas nas quais se formam fases intermetálicas. Palavras-chave: Ruído magnético Barkhausen; Aços inoxidáveis dúplex; Fase sigma; Ensaios não destrutivos. Abstract Duplex stainless steels have a structure normally composed of auteite and ferrite in approximately equal proportions. In order to attain control of its fabrication processes and performance, it is important to understand its microstructural evolution, due to the formation of intermetallic phases such as sigma (σ) and chi (χ), that may cause a severe deterioration of the mechanical properties of duplex stainless steels. In the present study, the evolution of sigma phase during heat treatments at temperatures in which intermetallic phases cam be formed (800ºC-900°C) was studied in a SAF2205 (DIN 1.4462/UNS31803) steel. A significant reduction of the intensity of Magnetic Barkhausen Noise (MBN) was observed with the increase of heat treatment time, indicating a decrease in the quantity of ferromagnetic phases. For 24-hour-long treatments, the Barkhausen Noise signal is almost completely enclosed by the background noise, indicating the existence of a very small volume fraction of ferrite. If proper calibration samples are to be produced, this technique may be a viable method for non-destructive evaluation of field components working under thermal conditions that may cause the formation of intermetallic phases.

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The use of magnetic Barkhausen (MBN) noise methods to detect the austenite to martensite phase transformation during cooling of steel specimens was explored, using three different configurations: conventional Barkhausen noise emission stimulated by an alternating magnetic field, the Okamura method, that measures magnetic noise emission under a fixed DC field and a novel experimental technique that measures spontaneous magnetic emission during transformation, in the absence of any external field. The phenomena associated with the phase transformation were also followed by electrical resistivity measurements and the resulting samples were characterized using optical and scanning electron microscopy. MBN measurements on a AISI D2 tool steel austenitized at 1473K and cooled to liquid nitrogen temperature exhibited a clear change near 225 K during cooling, corresponding to the Ms (martensite start ) temperature, as confirmed by resistivity measurements. Spontaneous magnetic noise emission measurements made in situ during cooling of a sample immerged in liquid nitrogen showed that individual “burst” phenomena could be detected, in a manner similar to acoustic emission (AE) measurements. This magnetic emission (ME) can thus be considered a new experimental tool for the study of martensite transformations in ferrous alloys.