TX 75083-3836, U.S.A., fax 01-972-952-9435. AbstractThe goal of matrix stimulation of carbonate reservoirs is to improve near wellbore conductivity by generating wormholes and increasing the effective wellbore radius, bypassing damaged areas. In naturally fractured carbonates, the wormholes connect the existing fractures, creates longer flow channels. Most widely used stimulation method in carbonate reservoirs is matrix acidization using HCl with various concentrations. The rapid reaction of HCl with carbonate matrix does not allow the reactive fluid to penetrate deep inside the formation before the acid spends.Therefore, the efficiency of conventional acid is limited, where deep penetration is needed. Stable emulsified acids are found very effective, to combat the challenge. The basic advantages of using emulsified acid are: generates longer wormholes by deep penetration into the formation; better zonal coverage; preferential stimulation of oil zones and less corrosive to workstring and downhole/surface equipment. Based on the extensive laboratory studies, a stable deep-penetrating emulsified acid has been developed for carbonate reservoirs. The formulation is a mixture of HCl with compatible additives, diesel and some suitable emulsifiers. The ratio of the dispersed acid and external diesel phase is maintained as 70:30. Stability of the system is a major concern for adequate retardation and penetration deep inside the reservoir. Stability of emulsion largely depends on reservoir temperature and the HLB number of emulsifier. Two surfactants were identified for the system and the HLB number has been maintained in the range of 5.1-5.2 by optimizing the ratio of two surfactants for achieving the maximum stability. The developed acid system has been applied in some wells of an offshore field of India with encouraging results. The field comprises of naturally fractured limestone formation with number of hydrocarbon bearing sands. This paper describes the development of the Deep Penetrating Emulsified Acid and its application in the field along with treatment methodology and outcomes.
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