Abstract-An improvement in the velocity resolution and quality of Mössbauer spectra has been applied to a group of ordinary chondrites. This improvement permitted us to carry out a more detailed study of the iron bearing phases in these samples than has previously been possible. Mössbauer spectra of 11 ordinary chondrites of L and H chemical groups were measured using 4096 channels and presented for further analysis in 1024 channels. Subspectra of the metal grains of several chondrites demonstrated the presence of at least two magnetic sextets related to the main Fe(Ni, Co) phases. Moreover, Mössbauer study of extracted metal grains from Tsarev L5 revealed three sextets and one singlet spectral components related to various α-Fe(Ni, Co), α′-Fe(Ni, Co), α 2 -Fe(Ni, Co), and γ-Fe(Ni, Co) phases. Each subspectrum of olivine and pyroxene in Mössbauer spectra of ordinary chondrites was fitted by superposition of two quadrupole doublets related to M1 and M2 sites in minerals for the first time. An analysis of relative areas and Mössbauer hyperfine parameters was performed and some differences for L and H chondrites as well as for M1 and M2 sites were observed. Mössbauer parameters of troilite and oxidized iron were analyzed. In contrast to a previous study with 512-channel spectra, the presence of oxidized iron was found in all chondrites.

No abstract

We studied the interior and the fusion crust of the recently recovered Ozerki L6 meteorite using optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy, X-ray diffraction (XRD), magnetization measurements, and M€ ossbauer spectroscopy. The phase composition of the interior and of the fusion crust was determined by means of SEM, XRD, and M€ ossbauer spectroscopy. The unit cell parameters for silicate crystals were evaluated from the X-ray diffractograms and were found the same for the interior and the fusion crust. Magnetization measurements revealed a decrease of the saturation magnetic moment in the fusion crust due to a decrease of Fe-Ni-Co alloy content. Both XRD and M€ ossbauer spectroscopy show the presence of magnesioferrite in the fusion crust. The temperatures of cation equilibrium distribution between the M1 and M2 sites in silicates calculated using the data obtained from XRD and M€ ossbauer spectroscopy appeared to be in a good consistency: 553 and 479 K for olivine and 1213 and 1202 K for orthopyroxene.

No abstract