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Thirty soil samples were analyzed for their properties and cadmium concentration in polluted and unpolluted sites of Isikwuato, Abia State, Nigeria. Polluted soils were more acidic (pH = 4.38) than unpolluted ones (pH = 5.22). Bulk density increased in polluted soils (1.51 g/cm 3 ). Higher average value of organic matter was recorded in polluted soils (mean value = 1.42 %) unlike 0.98 % found in unpolluted soils. Cadmium concentration was higher in polluted soils (0.76 mg/kg) contrasting with 0.02 mg/kg obtained in their unpolluted counterparts. Good relationship existed between exchangeable acidity and cadmium status in polluted soils (R = 0.83, R 2 = 0.77, N = 30) as opposed to values in unpolluted soils (R = 0.58, R 2 = 0.49, N = 30).

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ABSTRACT:The study investigated zinc availability in relation to selected soil properties in a crude-oil-polluted Eutric Tropofluvent in Egbema, Southeastern Nigeria. For this purpose, three treatments have been applied: unpolluted soil, polluted without vegetation and polluted with vegetation with five replicates arranged in a randomized complete block design. Guided by transect sampling technique, soil sampling was carried out in June 2008. Soil samples were collected from the three different land units using soil auger at a depth of 0-20 cm. Standard laboratory procedures were adopted in analysing the soils. Soil generated data were subjected to analysis of variance and correlation analysis. Results showed highly significant variation (p = 0.01) in bulk density, porosity, silt: clay ratio, pH, effective cation exchange capacity, percent base saturation, total nitrogen, organic matter, available phosphorus, calcium: magnesium ratio and zinc. It was found that zinc was higher in crude oil polluted soils than in non-polluted soil and it was below critical limits. Zinc availability in relation to selected soil properties in the crude oil polluted soils indicated that clay and organic matter did not affect zinc availability, while pH and effective cation exchange capacity did. A study on zinc dynamics in crude-oil-polluted soils will certainly provide further information on the management of crude-oil-polluted soils since it is one of the key micronutrient for crop productivity.

AB STRACT: Studies on seasonal changes of heavy metal concentration in soils provide vital information for best management options at all times. The study investigated temporal variation in concentration of heavy metals in three towns having automobile service centres in Imo State. The study site is characterized by two major seasons in a year. Heavy metals were found in both arable and automobile soils, but more concentrations were recorded on the latter. Mean values of Cd, Cr, Ni, Hg and Pb were 6.2 mg/kg, 4.7 mg/kg 6.5 mg/kg, 0.02 mg/kg and 71.9 mg/kg respectively in the dry season while 2.9 mg/kg Cd, 2.2 mg/kg Cr, 1.9 mg/kg Ni, 0.01 mg/kg Hg and 51.9 mg/kg Pb were recorded during the rainy season of the experimental period. Higher values of heavy metal concentration were found in automobile soils as follows: 18.1 mg/kg Cd, 12.0 mg/kg Cr, 16.3 mg/kg Ni, 4.8 mg/kg Hg and 312.8 mg/kg Pb in rainy season, and 15.1 mg/kg Cd, 8.1 mg/kg Cr, 11.9 mg/kg Ni 2.7 mg/kg Hg and 267.9 mg/kg Pb. However, Cd showed highest variability in arable soils during the dry season (CV=79%) while Hg varied widely in automobile soils in the rainy season (CV=54%).

This study analyzed relationships between soil properties and food crop production in Ebonyi State of southeast Nigeria. Free survey was conducted after three zones (Agbaja, Akaeze and Ikwo) in the state were purposely selected for representation of the soil sampling. Two types of sampling were conducted; Auger sampling at 0-20 and 20-40 cm depths and soil profile sampling. Annual crop yield data on maize and cassava for the state from 1988 to 2017 were collected from Agriculture Development Program. Variations in properties among soil horizons were obtained using coefficient of variations while soil parameters were regressed against crop yields to establish their relationships. Results showed that fine sand, total sand, bulk density, total porosity, soil pH, and available phosphorus significantly (p = 0.05) differ from 0-20 cm and 20-40 cm depths. Also, cassava yield correlated negatively with base saturation, and organic matter at 0.05 probability level; with exchangeable Ca and Na at 0.01 probabilities level but correlated positively with bulk density and available water capacity at 0.01 and 0.05 probability levels, respectively. Similarly, maize yield correlated negatively with available phosphorus and total nitrogen at 0.05 probability level; and with total porosity and exchangeable Ca at 0.01 probability level; and then correlated positively with available water capacity, and bulk density, at 0.01 probability level; with coarse sand at 0.05 probability level. However, soils of Ebonyi State are fertile but some of the chemical properties are still low, therefore, it is paramount to improve the quality of the soil to achieve improved food security in the state.

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