A unified approach to the computation of equilibrium in combustion products of oxygen mixtures overriched with hydrocarbon fuel, when both gaseous and condensed carbon phases may appear simultaneously among the components of chemical reaction, has been formulated. Within the framework of this approach, the problem of determining the equilibrium parameters (pressure, density, temperature, etc) of chemical reaction products produced at explosion of acetylene-oxygen mixture in a closed volume as the values of molar fraction of fuel (acetylene) vary up to the values when oxygen in the mixture is almost absent has been solved.
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