Terpenes U 0200 (R)-4-Menthenone in Reactions of 1,4-Conjugate and 1,3-Dipolar Addition. -Compared with common cyclic enones, (R)-4-menthenone exhibits considerably lower reactivity in the 1,4-conjugate addition of organometallic reagents and is even inert in Michael reactions and pyrazoline formation. -(ISHMURATOV, G. Y.; LATYPOVA, E. R.; KHARISOV, P. Y.; MUSLUKHOV, R. R.; BANNOVA, A. A.; TALIPOV, R. F.; TOLSTIKOV, G. A.; Russ.
The author’s data on ozonolytic decyclization (ring opening) of (R)-4- menthene-3-one and its alkylated analogues and application of non-peroxide ozonolysis products in the synthesis of optically active low molecular weight bioregulators including the insects pheromones and juvenoids were generalized. The results of comparative reactivity of the mentioned above mono-terpenoid in the set of α, β-unsaturated cyclic enones were represented.
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