Publication costs assisted by the U. S. Energy Research and Development AdminlstrationRate constants for the reactions of H atoms, formed by mercury photosensitization of H2-substrate mixtures at 32 O C , with (CH3),SiH4-, and (C2HS),SiH4-, for n = 0, 1,2,3; with (CH3),SiD4-, for n = 0, 1; and with Si2H6, Si2D6, GeH4, and Ge2H6 have been determined in experiments involving the competitive reaction of H atoms with C2H4 and i-C4HB. Activation energies, estimated from these rate constants, have been combined with thermochemical data by means of a bond-energy-bond-order (BEBO) method of calculation to yield a consistent set of dissociation energies for Si-H bonds in the R,SiH4-, series of silanes for n = 0, 1, 2, 3.
A direct 15N method was used to measure N2 and N2O flux in flooded rice (Oryza sativa L.) fields. The method involved application of a highly 15N‐enriched source to a 0.4‐m by 0.4‐m microplot, collection of evolved N2 and N2O in a chamber placed over the flood‐water, removal of NH3 from the air sample, conversion of some (N2 + N2O)‐N in the air sample to NH+4‐N, and determination of 15N content with a mass spectrometer. The flux of (N2 + N2O)‐15N was measured for 17 d following urea application by three methods, each replicated four times, on a Vertic Tropaquept. In all cases, the (N2 + N2O)‐15N flux was much smaller than total gaseous 15N loss as estimated from unaccounted for 15N in the 15N balance after 18 d. The (N2 + N2O)‐15N flux and total 15N loss were 1.1 and 40%, respectively, following basal broadcast and incorporation of 58 kg urea‐N ha−1 with 2‐cm standing water; they decreased to 0.2 and 26%, respectively, when the urea basal incorporation was without standing water. The (N2 + N2O)‐15N flux and total 15N loss were 0.5 and 46%, respectively, following application of 44 kg urea‐N ha−1 to 50‐mm floodwater at 10 d after transplanting. The methodology could detect a flux of 10 g N ha−1 d−1 from the added 59 to 64 atom % 15N‐labeled urea. Additional studies with 15N‐labeled NO‐3 evaluated the possibility that the low (N2 + N2O)‐15N flux was due to incomplete recovery of N2 and N2O formed from added fertilizer. Direct recovery of (N2 + N2O)‐15N following addition of labeled NO‐3 ranged from 41 to 73% of the total 15N loss. No 15N was lost by leaching or runoff, and dissolved N2O in the floodwater calculated from published solubility data was less than 1% of the added 15N.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.