The fragmentation pattern of metal complexes of 2-butyl-8-hydroxyquinoline depends essentially upon the ability of the metal ion to absorb an electron, i.e. to exist in a stable monovalent form. In this case the main fragment is formed by loss of a molecule of 2-n-butyl-8-hydroxyquinoline, otherwise an ethyl radical is eliminated.
Zusammenfassung-Das Fragmentierungsrnuster der Metallkomplexe des 2-Butyl-8-hydroxychinolinshangt im wesentlichen davon ab, ob das Metall-Ion unter Aufnahme eines Elektrons in eine stabile einwertige Form iibergehen kann oder nicht. Im ersten Fall entsteht das Hauptfragment durch Verlust eines Molekiils 2-n-Butyl-8-hydroxychinolin, im zweiten durch Abspaltung eines Athylradikals.
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