Ternary alloy CdSSe nanowires and nanoribbons were successfully grown through a one-step thermal evaporation route using Au as a catalyst. The nanostructures obtained are uniform in diameter, and have smooth surfaces. High-resolution transmission electron microscopy, energy dispersive x-ray spectra and x-ray diffraction showed that both the nanowires and the nanoribbons have high-quality single-crystalline nature, and their compositions can be determined as CdS 0.6 Se 0.4 and CdS 0.3 Se 0.7 , respectively. The mechanisms of formation of these two different nanostructures were discussed. The photoluminescence measurements showed very strong band-edge emission for both samples, which further demonstrates the single-crystal nature of the as-obtained CdSSe alloys. This finding may be extended for fabricating other composition-tunable 1D ternary alloy nanostructures.
Electroluminescence power profiles and 2D micropatterns have been obtained from InAsSb/InAs planar LEDs tuned at several wavelengths within the 3-5 µm band. Light confined to a small region around the top opaque contact was observed (cw mode, I > 10 mA, T = 300 K). A computer simulation showed that the reason behind the decrease of the emitting area is the current crowding that ensures non-uniform injection into the active region. The effect becomes more apparent in longer wavelength devices (emitting areas of 3.4 and 4.2 µm emitting devices are related as >10 : 1), providing direct evidence that the current crowding is affected by the bandgap energy of an active layer.
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