We present measurements of the stable carbon isotope ratio in air extracted from Antarctic ice core and firn samples. The same samples were previously used by Etheridge and co-workers to construct a high precision 1000-year record of atmospheric CO 2 concentration, featuring a close link between the ice and modern records and high-time resolution. Here, we start by confirming the trend in the Cape Grim in situ d13C record from 1982 to 1996, and extend it back to 1978 using the Cape Grim Air Archive. The firn air d13C agrees with the Cape Grim record, but only after correction for gravitational separation at depth, for diffusion effects associated with disequilibrium between the atmosphere and firm, and allowance for a latidudinal gradient in d13C between Cape Grim and the Antarctic coast. Complex calibration strategies are required to cope with several additional systematic influences on the ice core d13C record. Errors are assigned to each ice core value to reflect statistical and systematic biases (between ±0.025‰ and ±0.07‰); uncertainties (of up to ±0.05‰) between core-versus-core, ice-versus-firn and firn-versus-troposphere are described separately. An almost continuous atmospheric history of d13C over 1000 years results, exhibiting significant decadal-to-century scale variability unlike that from earlier proxy records. The decrease in d13C from 1860 to 1960 involves a series of steps confirming enhanced sensitivity of d13C to decadal timescale-forcing, compared to the CO 2 record. Synchronous with a ''Little Ice Age'' CO 2 decrease, an enhancement of d13C implies a terrestrial response to cooler temperatures. Between 1200 AD and 1600 AD, the atmospheric d13C appear stable.
Hydrographical changes of the southern Indian Ocean over the last 230 kyr, is reconstructed using a 17‐m‐long sediment core (MD 88 770; 46°01′S 96°28′E, 3290m). The oxygen and carbon isotopic composition of planktonic (N. pachyderma sinistra and G. bulloides) and benthic (Cibicidoides wuellerstorfi, Epistominella exigua, and Melonis barleeanum) foraminifera have been analysed. Changes in sea surface temperatures (SST) are calculated using diatom and foraminiferal transfer functions. A new core top calibration for the Southern Ocean allows an extension of the method developed in the North Atlantic to estimate paleosalinities (Duplessy et al., 1991). The age scale is built using accelerator mass spectrometry (AMS) 14C dating of N. pachyderma s. for the last 35 kyr, and an astronomical age scale beyond. Changes in surface temperature and salinity clearly lead (by 3 to 7 kyr) deep water variations. Thus changes in deep water circulation are not the cause of the early response of the surface Southern Ocean to climatic changes. We suggest that the early warming and cooling of the Southern Ocean result from at least two processes acting in different orbital bands and latitudes: (1) seasonality modulated by obliquity affects the high‐latitude ocean surface albedo (sea ice coverage) and heat transfer to and from the atmosphere; (2) low‐latitude insolation modulated by precession influences directly the atmosphere dynamic and related precipitation/ evaporation changes, which may significantly change heat transfer to the high southern latitudes, through their control on latitudinal distribution of the major frontal zones and on the conditions of intermediate and deep water formation.
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