We determined abundances of Na and Zr in the atmospheres of 237 RGB stars in Galactic globular cluster (GGC) 47 Tuc (NGC 104), with a primary objective of investigating possible differences between the abundances of Zr in the first generation (1P) and second generation (2P) stars. For the abundance analysis, we used archival UVES/GIRAFFE spectra obtained during three different observing programmes. Abundances were determined from two Na I and three Zr I lines, using 1D hydrostatic ATLAS9 model atmospheres. The target stars for the abundance analysis were limited to those with 4200 ≤ Teff ≤ 4800 K. This is the largest sample of GGC stars in which Na and Zr abundances have been studied so far. While our mean [Na/Fe] and [Zr/Fe] ratios agree well with those determined in the earlier studies, we find a weak but statistically significant correlation in the [Zr/Fe] – [Na/Fe] plane. A comparison of the mean [Zr/Fe] abundance ratios in the 1P and 2P stars suggests a small but statistically significant Zr over-abundance in the 2P stars, ∆[Zr/Fe]2P−1P ≈ +0.06 dex. Also, our analysis shows that stars enriched in both Zr and Na are more centrally concentrated. However, we find no correlation between their distance from the cluster centre and their full spatial velocity, as indicated by the velocity dispersions at different mean values of [Zr/Fe] and [Na/Fe]. While there may be some influence of CN line blends on the determined Zr abundances, it seems very unlikely that the detected Zr–Na correlation, for the slightly higher Zr abundances in the 2P stars, would be caused by the CN blending alone. The obtained results indicate that, in 47 Tuc, some amount of Zr should have been synthesised by the same polluters that enriched 2P stars with the light elements. While sizeable amounts of Zr may be synthesised by both AGB stars (M ~ 1.5–5 M⊙) and massive rotating stars (M ~ 12–25 M⊙, υrot > 150 km s−1), our data alone do not allow us to distinguish which of the two scenarios, or whether or not a combination of both, could have operated in this GGC.

Context. While most (if not all) Type I Galactic globular clusters (GGCs) are characterised by spreads in the abundances of light chemical elements (e.g. Li, N, O, Na, Mg, Al), it is not yet well established whether similar spreads may exist in s-process elements as well. Aims. We investigated the possible difference in Ba abundance between the primordial (1P) and polluted (2P) stars in the Galactic globular cluster (GGC) 47 Tuc (NGC 104). For this purpose, we obtained homogeneous abundances of Fe, Na, and Ba in a sample of 261 red giant branch (RGB) stars, which comprises the largest sample used for Na and Ba abundance analysis in any GGC so far. Methods. Abundances of Na and Ba were determined using archival GIRAFFE/VLT spectra and 1D non-local thermodynamic equilibrium (NLTE) abundance analysis methodology. Results. Contrary to the finding of Gratton et al. (2013, A&A, 549, A41), we did not detect any significant Ba–Na correlation or 2P–1P Ba abundance difference in the sample of 261 RGB stars in 47 Tuc. This corroborates the result of D’Orazi et al. (2010, ApJ, 719, L213), who found no statistically significant Ba–Na correlation in 110 RGB stars in this GGC. The average barium-to-iron ratio obtained in the sample of 261 RGB stars, ⟨[Ba/Fe]1D NLTE⟩ = −0.01 ± 0.06, agrees well with those determined in Galactic field stars at this metallicity and may therefore represent the abundance of primordial proto-cluster gas that has not been altered during the subsequent chemical evolution of the cluster.

We determined zirconium abundance in the atmospheres of 327 red giant branch (RGB) stars in the globular cluster 47 Tuc. The 1D LTE abundances were obtained from the archival VLT GIRAFFE spectra, using 1D hydrostatic ATLAS9 stellar model atmospheres and synthetic Zr I line profiles computed with the SYNTHE package. The average zirconium abundance determined in the sample of RGB stars, [Zr/Fe] = +0.38 ± 0.12, agrees well with zirconium abundances obtained at this metallicity in the Galactic field stars, as well as with those observed in other Galactic globular clusters.

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