Detailed sedimentological, facies and numerical cycle analysis, combined with magnetostratigraphy, have been made in a number of boreholes in the Pannonian Basin, in order to study the causes of relative water-level changes and the history of the basin subsidence. Subsidence and infilling of the Pannonian Basin, which was an isolated lake at that time occurred mainly during the Late Miocene and Pliocene. The subsidence history was remarkably different in the individual sub-basins: early thermal subsidence was interrupted in the southern part of the basin, while high sedimentation rate and continuous subsidence was detected in the northeastern sub-basin. Three regional unconformities were detected in the Late Neogene Pannonian Basin fill, which represent 0.5 and 7.5 Ma time spans corresponding to single and composite unconformities. Consequently two main sequences build up the Late Neogene Pannonian Basin fill: a Late Miocene and a Pliocene one. Within the Late Miocene sequence there are smaller sedimentary cycles most probably corresponding to climatically driven relative lake-level changes in the Milankovitch frequency band. Considering the periods, the estimated values for precession and eccentricity in this study (19 and 370 ka) are close to the usually cited ones. In the case of obliquity the calculated period (71 ka) slightly deviates from the generally accepted number. Based on the relative amplitudes of oscillations, precession (sixth order) and obliquity (fifth order) cycles had the most significant impact on the sedimentation. Eccentricity caused cycles (fourth order) are poorly detectable in the sediments. The longer term (third order) cycles had very slight influence on the sedimentation pattern. Progradation, recorded in the Late Miocene sequence, correlates poorly in time within the basin. The dominant controls of this process probably were changes of basin subsidence rate and the very high sedimentation rate. The slow, upward trend of silt and sand bed thickness as well as that of the grain size also reflects the local progradation.
Large, irregular volumes of altered, friable Triassic dolomite with poorly recognizable depositional fabrics crop out in the Buda Mountains, Hungary. These rock volumes are characterized by powderlike, chalky, soft, whitish gray microporous carbonates, referred to as "pulverized dolomite". This is interpreted as the result of corrosion of carbonates along microfractures. The pulverized dolomite is commonly associated with silica and clay cementation ("silicification") and "mineralization" of ironrich minerals, barite, sphalerite, galena, fluorite, calcite, dolomite and others, clearly pointing out hydrothermal Mississippi Valley Type (MVT) conditions.The pulverization, silicification and mineralization are considered to be a diagenetic facies association (PSM facies). Tectonic shear corridors played an important role in the development of PSM facies as carriers of hydrothermal fluids, but the geometry of the altered units is very irregular and cross-cuts different Triassic depositional facies in addition to Eocene limestone and MiddleUpper Miocene sediments. The PSM facies represents the early stages of hydrothermal alteration (i.e. the burial phase) that was later modified by thermal mixing zones. Pulverized dolomite bodies that reached the surface were strongly affected by meteoric fluids; peculiar speleo-concretions were formed by calcite cementation of the powdery dolomite clasts.The altered carbonates show major porosity development whereas the unaltered carbonates present only minor porosity. The size and lithologic contrast of the altered geobodies makes them detectable by geophysical methods of mineral and hydrocarbon exploration.
Platform carbonates of the Upper Triassic Dachstein Limestone in Naszály Hill have been karstified extensively over the past 200 million years. They provide an excellent example of polyphase karstic diagenesis that is probably typical of many subaerially exposed carbonate sequences. Seven karstic phases are recognized in the area, each of which include polyphase karstic events. The first karst phase was associated with the Löfer cycles. Meteoric waters caused dissolution; enlarged fractures and cavities, were filled by marine and/or vadose silts and cement. The second karst phase was caused by local tectonic movements. Bedding‐plane‐controlled phreatic caves were formed, and filled by silts. The third karst phase lasted from the end of the Triassic to the Eocene. This was a regional, multiphase karstic event related to younger composite unconformities. Bauxitic fill is the most characteristic product of this phase. The karst terrain reached its mature or senile stage with very little porosity. Narrow veins and floating rafts of white calcite marks karst phase 4, which resulted from hydrothermal activity associated with Palaeogene magmatism. The early Rupelian phase of Alpine uplift caused large‐scale rejuvenation of the former karst terrain (karst phase 5). Subsequently Naszály Hill was buried as an area of juvenile karst with significant porosity. A second period of hydrothermal activity in the area (karst phase 6) was induced by Miocene volcanism, which resulted in wide, pale green calcite veins. Finally karst phase 7 was of tectonic origin. Following the most recent, Miocene uplift of the Naszály Hill, the carbonates have again become the site of vadose karst development.
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