ILLUSTRATIONS 4. The facility burns a mixture of fuel oil and natural gas. The oil contains about 1 percent total sulfur and the natural gas about 9.6 kg of sulfur per 10" m^. The oil/gas consumption ratio, however, is variable over time and therefore the amount of sulfur emitted is also highly variable. Our study should be viewed as an integrated "snapshot" of the influence of the power plant over about a one-year period (the plant material sampled was from the previous growing season) and any extrapolation of these data should be done with appropriate caution. 5. All plant, soil, and oil samples were analyzed for the total concentration of twenty-four elements. Also, all plant and oil samples, and selected soil and seawater samples, were analyzed for stable sulfur isotope abundances. 6. Sodium and total sulfur levels in plant leaves decrease with increasing distance from the coast along all three traverses. These trends are strong evidence that the sea is a source of these elements in vegetation. Total sulfur levels along the power plant traverse are only slightly elevated when compared to samples along the other two traverses. 7. The relative abundance of stable sulfur isotopes in vegetation helps discriminate the sulfur in vegetation that is being contributed by the sea from that which is being contributed by the operations of the power plant. Fuel oil samples possessed 634 sulfur values equal to about zero °/ e « and the only similar s^sulfur values in vegetation were found at a site 0.97 km from the power plant. Marine sulfate has a ^sulfur of about +20°/«« and samples collected elsewhere near the coast appear to reflect the influence of the addition of sulfate with this large positive value. 8. Vegetation and soil samples collected along a north-south traverse (traverse 4) progressing away from a portland cement manufacturing facility showed no meaningful element concentration versus distance trends. 9. Except for collections along traverse 4 (cement plant/agriculture traverse), the soils encountered in this study were highly variable in their composition and their utility as a sampling medium for the definition of measurable power plant emission effects is limited. 10. No significant difference was found between the element concentration of plant leaf samples collected while wearing rubber gloves to identical samples collected while not wearing gloves. 11. Samples of young and old Casuarina equisetifolia wood from trunks of 10-year-old trees showed no historical difference in element concentrations between the sections. Trends of decreasing molybdenum concentration in young and old wood with increasing distance from the coast and power plant could not be explained as being the result of operations at the electrical generation facility.
Sulfur was determined in Parmelia sulcata and P. chlorochroa by combustion of the sample and infrared detection of evolved sulfur dioxide using an automated sulfur analyzer.Vanadium pentoxide was used as a combustion accelerator. Pelletization of the sample prior to combustion was not found advantageous. Washing studies showed that leaching of sulfur was not a major factor in the sample preparation.The combustion-IR analysis usually gave higher sulfur content than the turbidimetric analysis as well as shorter analysis time.Relative standard deviations of less than 7% were obtained by the combustion-IR technique when sulfur levels in lichens ranged from 0.05-0.20%.Determination of sulfur in National Bureau of Standards orchard leaves standard reference material showed good agreement between the combustion-IR technique and other instrumental procedures.
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