The magnetocaloric effect (MCE) in paramagnetic materials has been widely used for attaining very low temperatures by applying a magnetic field isothermally and removing it adiabatically. The effect can also be exploited for room-temperature refrigeration by using giant MCE materials. Here we report on an inverse situation in Ni-Mn-Sn alloys, whereby applying a magnetic field adiabatically, rather than removing it, causes the sample to cool. This has been known to occur in some intermetallic compounds, for which a moderate entropy increase can be induced when a field is applied, thus giving rise to an inverse magnetocaloric effect. However, the entropy change found for some ferromagnetic Ni-Mn-Sn alloys is just as large as that reported for giant MCE materials, but with opposite sign. The giant inverse MCE has its origin in a martensitic phase transformation that modifies the magnetic exchange interactions through the change in the lattice parameters.

Applying a magnetic field to a ferromagnetic Ni 50 Mn 34 In 16 alloy in the martensitic state induces a structural phase transition to the austenitic state. This is accompanied by a strain which recovers on removing the magnetic field, giving the system a magnetically superelastic character. A further property of this alloy is that it also shows the inverse magnetocaloric effect. The magnetic superelasticity and the inverse magnetocaloric effect in Ni-Mn-In and their association with the first-order structural transition are studied by magnetization, strain, and neutron-diffraction studies under magnetic field.

The structural and magnetic properties of stoichiometric Ni 2 MnAl are studied to clarify the conditions for ferromagnetic and antiferromagnetic ordering claimed to occur in this compound. X-ray and magnetization measurements show that although a single phase B2 structure can be stabilized at room temperature, a single L2 1 phase is not readily stabilized, but rather a mixed L2 1 ϩB2 state occurs. The mixed state incorporates ferromagnetic and antiferromagnetic parts for which close-lying Curie and a Néel temperatures can be identified from magnetization measurements.

At certain compositions Ni-Mn-X Heusler alloys ͑X: group IIIA-VA elements͒ undergo martensitic transformations, and many of them exhibit inverse magnetocaloric effects. In alloys where X is Sn, the isothermal entropy change is largest among the Heusler alloys, particularly in Ni 50 Mn 37 Sn 13 , where it reaches a value of 20 J kg −1 K −1 for a field of 5 T. We substitute Ni with Fe and Co in this alloy, each in amounts of 1 and 3 at % to perturb the electronic concentration and examine the resulting changes in the magnetocaloric properties. Increasing both Fe and Co concentrations causes the martensitic transition temperature to decrease, whereby the substitution by Co at both compositions or substituting 1 at % Fe leads to a decrease in the magnetocaloric effect. On the other hand, the magnetocaloric effect in the alloy with 3 at % Fe leads to an increase in the value of the entropy change to about 30 J kg −1 K −1 at 5 T.

The ferromagnetic interstitial iron compound Fe(3)C (cementite) is expected to have Invar properties, whereby a high-moment to low-moment transition should occur when the atomic volume is reduced below a critical value. We, therefore, examine the pressure dependence of the Fe K-edge x-ray magnetic circular dichroism in Fe(3)C at ambient temperature and pressures up to 20 GPa. We find clear evidence for a high-moment to low-moment transition around 10 GPa.