Although femtosecond lasers have proved to be of great utility for micromachining within bulk transparent materials, little is known about the fundamental physics that drive the process. Depending on the laser intensity delivered to the sample, any of three types of feature can be written into the glass. We observed that in the intermediate regime there is a correlation among the negative sign of the effective index change, the presence of anisotropic reflection, and birefringence. We propose a model that can explain all three principal characteristics. Results show that the local index change can be as high as 10(-1).

A remarkable phenomenon in ultrafast laser processing of transparent materials, in particular, silica glass, manifested as a change in material modification by reversing the writing direction is observed. The effect resembles writing with a quill pen and is interpreted in terms of anisotropic trapping of electron plasma by a tilted front of the ultrashort laser pulse along the writing direction.

In this letter we report the different response to temperature displayed by isotropic femtosecond written structures ͑type I_fs͒, and anisotropic ones ͑type II_fs͒, which are characterized by the presence of a self-assembled subwavelength periodic structure within the irradiated volume. We observe that the anisotropic structures display an extraordinary annealing behavior, namely, their photoinduced change in refractive index increases with the annealing temperature. We explain our experimental results with a theoretical model.

We demonstrate maskless, single-step fabrication of strongly birefringent Fresnel zone plates by focusing of femtosecond laser pulses deep within silica substrates. The process allows us to produce alternate zone rings directly by inducing a local refractive-index modification of the order of n~10(-2) . The embedded zone plates shown in this Letter exhibit efficiencies that vary by as much as a factor of ~6 for orthogonal polarizations. Focal lengths of primary and secondary foci are shown to compare well with theory.

Self-assembled, sub-wavelength periodic structures are induced in fused silica by a tightly focused, linearly polarized, femtosecond laser beam. Two different types of periodic structures, the main one with period (Lambda(E)) in the direction of the laser beam polarization and the second with period (Lambda(k)) in the direction of the light propagation, are identified from the cross-sectional images of the modified regions using scanning electron microscopy. We demonstrate the spatial coherence of these nanogratings in the plane perpendicular to the beam propagation direction. The range of effective pulse energy which could produce nanogratings narrows when the pulse repetition rate of writing laser increases. The period Lambda(E) is proportional to the wavelength of the writing laser and period Lambda(k) in the head of the modified region remains approximately the wavelength of light in fused silica.