A novel hybrid material polyaniline@MIL-101 was synthesized and characterized. The obtained compound shows excellent selectivity towards CO2over nitrogen.
A simple and convenient procedure for the production of highly dispersed porous Co-Pt alloys to be used as catalysts for the synthesis of nanostructured carbon fibers (CNF) has been developed. The technique is based on the thermal decomposition of specially synthesized multicomponent precursors in a reducing atmosphere. A series of porous single-phase alloys Co-Pt (10–75 at% Pt) have been synthesized. The alloys containing 75 and 50 at% Pt were identified by the x-ray diffraction analysis as the intermetallics CoPt3 and CoPt, respectively. Within the region of 10–35 at% Pt, the synthesized alloys are represented by Co1−x
Pt
x
random solid solutions with face-centered cubic lattice. The alloys obtained are characterized by a porous structure consisting of assembled fragments with a size of 50–150 nm. The obtained alloys were tested in the catalytic chemical vapor deposition of the ethylene to CNF. A significant synergistic effect between Co and Pt in the synthesis of carbon nanomaterials (CNMs) was revealed. The yield of CNF (for 30 min reaction) for catalysts containing 25–35 at% Pt was 30–38 g(CNF)/g(cat), whereas those for Co (100%) and Pt (100%) samples were as low as 5.6 and >0.1 g(CNF)/g(cat), respectively. The produced CNM composed of fibers with a segmented structure was shown to be characterized by a rather high specific surface area (200–250 m2 g−1) and structural homogeneity.
Single-walled carbon nanotubes (SWCNTs) with their high surface area, electrical conductivity, mechanical strength and elasticity are an ideal component for the development of composite electrode materials for batteries. Red phosphorus has a very high theoretical capacity with respect to lithium, but has poor conductivity and expends considerably as a result of the reaction with lithium ions. In this work, we compare the electrochemical performance of commercial SWCNTs with red phosphorus deposited on the outer surface of nanotubes and/or encapsulated in internal channels of nanotubes in lithium-ion batteries. External phosphorus, condensed from vapors, is easily oxidized upon contact with the environment and only the un-oxidized phosphorus cores participate in electrochemical reactions. The support of the SWCNT network ensures a stable long-term cycling for these phosphorus particles. The tubular space inside the SWCNTs stimulate the formation of chain phosphorus structures. The chains reversibly interact with lithium ions and provide a specific capacity of 1545 mAh·g−1 (calculated on the mass of phosphorus in the sample) at a current density of 0.1 A·g−1. As compared to the sample containing external phosphorus, SWCNTs with encapsulated phosphorus demonstrate higher reaction rates and a slight loss of initial capacity (~7%) on the 1000th cycle at 5 A·g−1.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.