Mono and dinuclear phosphine complexes of beryllium halides [(PMe3)2BeXit>2], [(PMe3)BeX2]2 and [(PCy3)BeX2]2 (X = Cl, Br, I) were synthesised and characterised via NMR and IR spectroscopy as well...
The stability in water and at pH = 7.2, substitution reactions with Tu, 5’-GMP, GSH and l-Met, DNA/BSA interactions, cytotoxicity, DFT and molecular docking of gold(iii) complexes with phenanthroline derivatives as inert ligands were studied.
Three dinuclear complexes [Pd2(tpbd)Cl2]Cl2 (PP1), [Pt2(tpbd)Cl2]Cl2 (PP2) and [PdPt(tpbd)Cl2]Cl2 (PP3) (tpbd = N,N,N’,N’-tetrakis(2-pyridylmethyl)benzene-1,4-diamine) have been synthesized, characterized and the protonation constants of their corresponding diaqua analogues have been determined. Also,...
Within this paper is presented the synthesis and structural characterization of three newly synthesized osmium(II) complexes Os1-3, with the chemical formula [OsIILCl2H2O], [L=2,6-bis(5-tert-butyl-1H-pyrazol-3-yl)pyridine (for Os1), 2,6-bis(5-tert-butyl-1-methyl-1H-pyrazol-3-yl)pyridine (for Os2) or 2,2′:6′,2″-terpyridine...
A rhodium(iii) complex with 1,2,4-triazole and a pincer type nitrogen-donor ligand was synthesized, and its interaction with biomolecules was examined.
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