This article discusses the potential applications of natural polysaccharide-based graphene oxide nanomaterials in the field of wastewater remediation through the removal of organic and synthetic dyes. Being highly toxic, carcinogenic, and nonbiodegradable, dyes disposed from textile, paper, and printing industries etc. pose a serious threat to various life forms on earth. Recently, there has been an increased interest in the amalgamation of biopolymers, such as polysaccharides, with the high adsorption efficiency of graphene oxide. Polysaccharides, apart from being nontoxic, low cost, and eco-friendly, possess a variety of functional groups enabling them to be easily tuned for the desired applications. When grafted with GO nanosheets, they give rise to unique nanomaterials possessing diverse applications, especially in the eradication of harmful contaminants from wastewater. This review is an attempt to give consolidated and detailed information on different aspects of the adsorption behavior of various potentially low-cost polysaccharide-based GO nanoadsorbents toward lethal dyes. The characterization techniques used, adsorption isotherms, kinetics, thermodynamic behavior, recyclability, and swelling properties as well as the adsorption mechanism have been outlined in this article. The whole anthology of literature reports excellent dye removal efficiency with significant regeneration performance making these nanoadsorbents promising candidates for practical applications. In view of all aspects, this review recommends the use of such sustainable adsorbents with a further search toward obtaining the polysaccharides from natural wastes.
The present study
is focused on the synthesis of prominent magnetic
graphene oxide/chitin nanocomposites, which behaves as an adsorbent
for organic dyes under visible light. The nanocomposites were characterized
using physicochemical techniques such as X-ray diffraction, Fourier
transform infrared spectroscopy, Raman spectroscopy, vibrating-sample
magnetometer, scanning electron microscopy, and transmission electron
microscopy. A band gap energy of 2.01 eV was evaluated from Tauc and
Davis–Mott plots. Batch adsorption studies were performed on
crystal violet and methylene blue dyes with varying parameters such
as time, pH, concentration, dosage, and temperature, which resulted
to excellent adsorption activities of 403.78 mg/g for crystal violet
and 332.61 mg/g for methylene blue. The as-synthesized nanocomposite
showed excellent recovery capability, retaining its adsorption efficiency
even after nine cycles of regeneration. The adsorption equilibrium
data fitted well into the pseudo-second-order model and Langmuir isotherm
model, while the spontaneity and exothermic nature of the adsorption
phenomenon are demonstrated by thermodynamic studies. A comparative
adsorption study results to a selective adsorption of cationic dyes
over anionic ones, which goes in conformity with the high negative
value of zeta potential obtained at neutral pH.
Magnetic Graphene Oxide nanocomposite prepared by the co-precipitation method based on concept of nanoarchitectonics. In co-precipitation method, Graphene oxide converts into Magnetic graphene oxide nanocomposite with uniform deposition of Fe3O4 nano particles
on the surface of Graphene oxide. Field Emission Scanning Electron Microscopy spectroscopy technique reveals the size (~2.5 nm) and uniformity of Fe3O4 nano particles on Graphene oxide surface. The other properties characterized by Scanning electron microscopy, Raman
spectroscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy and vibrating-sample magnetometer. For Adsorption process, time, temperature, dose of adsorbent, initial concentration of dye solution and pH factors are optimize for Rhodamine 6G dye. Kinetic data expressed by Pseudo
first order model and Pseudo second order model. Langmuir, Freundlich and Temkin isotherms used to evaluate the adsorption isotherm of Rhodamine 6G onto the surface of Magnetic graphene oxide nanocomposite and thermodynamic parameters tell us about the nature of reaction.
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