In order to modify the surface of light metals and alloys, plasma electrolytic oxidation (PEO) is a useful electrochemical technique. During the oxidation process, by applying a positive high voltage greater than the dielectric breakdown value of the oxide layer, the formation of a ceramic film onto the substrate material is enabled. The resulting surface presents hardness, chemical stability, biocompatibility, and increased corrosion wear resistance. The current study aims to investigate the corrosion resistance and tribological properties of PEO-modified coatings on titanium substrates produced by applying either direct or pulsed current in a silicate-alkaline electrolyte. In this way, a uniform TiO2 layer is formed, and subsequently, electrophoretic deposition of hydroxyapatite particles (HAP) is performed. The morpho-structural characteristics and chemical composition of the resulting coatings are investigated using scanning electron microscopy combined with energy dispersive spectroscopy analysis and X-ray diffraction. Dry sliding wear testing of the TiO2 and HAP-modified TiO2 coatings were carried out using a ball-on-disc configuration, while the corrosion resistance was electrochemically evaluated at 37 °C in a Ringer’s solution. The corrosion rates of the investigated samples decreased significantly, up to two orders of magnitude, when the PEO treatment was applied, while the wear rate was 50% lower compared to the untreated titanium substrate.

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Amorphous alloys have emerged as an important class of advanced materials that own a combination of properties, such as mechanical strength, hardness, high elasticity modulus and a very good corrosion resistance. Since the number of amorphous structures alloys increased in the last decades, ways of joining such materials were studied in order to produce complex structures or increase their size. Thus, if this kind of complex products are obtained, it will diversify their applicability in multiple and various domains. For this research two ways of joining amorphous ribbons has been studied: solid state welding and radiant energy welding. For the radiant energy welding process, it was selected electron beam welding (EBW) method and for the solid-state welding process, ultrasonic welding (UW) method was chosen. Seeing that these methods have found applicability in industries, a comparative study was done in order to see which one offers the best outcome. Recently, in the last years, such products were embedded in a polymer matrix, creating thus, composite materials that have improved mechanical properties. This raised curiosity for major industries, such as aero-space, medical and automotive. Amorphous ribbons from Ni-Fe-Cr-Si-B and Al-Ni-Nd-Co alloy families were welded by EBW method, and Cu-Zr-Al amorphous ribbons were welded by the UW method. Microstructure characterization has been performed by SEM, EDX, XRD and DSC analyses.

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