One of the most relevant negative characteristics of high-capacity cathodes for lithium batteries is indeed non-flat voltage-time (V-t) or voltage-capacity (V-C) behaviour during charge-discharge. A clear rationale for this behaviour has not yet been addressed in the literature. Here, by means of density functional theory (DFT) calculations corroborated by basic experimental electrochemical characterization, we investigated both the thermodynamic and the kinetic aspects relevant to voltage variations during charge-discharge of Li 2 FeSiO 4 intended as a model case. A simple physical model allowed us to take into account all the experimental evidence. We suggested that voltage deviations from its theoretical value are due to the formation of undesired delithiated structures caused by concentration gradients. We also related voltage behaviour to relevant quantities such as reaction energies, lithium diffusion coefficients, and particle size, so suggesting some strategies for optimization of materials.
Methodology
Experimental detailsLi 2 FeSiO 4 /C was synthesized by both nitrate sol-gel and solid state synthesis methods. For the sol-gel method, lithium † Electronic supplementary information (ESI) available: V-C diagrams of discharge measurements of our sample with different rates, and absolute value of slope of charge-discharge diagrams versus square root of the applied rates. See
We investigate the influence of particle size and crystal orientation on the electrochemical behavior of carboncoated LiFePO 4 prepared by a hydrothermal synthesis in the presence of a polymeric surfactant and a source of carbon. We evaluated the charge/discharge profiles of two samples, one constituted by particles in the micrometer range with a platelet-like shape (large ac facet and (020) crystal orientation) and another made of sub-micrometer-rounded particles with a random crystal orientation. At low current rates the crystal orientation seems to be the prevailing factor, whereas at high current rates smaller particles can allow a shorter electronic conduction path, so reducing the resistance experienced by Li ions during diffusion.
The results of the structural determination of Li2MnO3 from X-ray powder diffraction data and the refinement by the Rietveld technique are presented. The Li2MnO3 structure has a monoclinic cell with space group C2/m(Z=4) and cell parameters a=4.9246 (1) and S=3.52. Such a so~'ution agrees with a single-crystal structure determination previously reported in the literature and allows other hypotheses to be rejected. plane parallel to the ac plane was underlined that the other authors did not consider.The aim of this work is to demonstrate that conventional laboratory X-ray powder diffraction data may very well be used for structure determination of compounds of low symmetry, like Li2MnO3. For such a compound, a detailed comparison with the pertinent single-crystal data is possible. The programs actually available for the treatment of powder data are sufficiently reliable, and represent a valid choice when single-crystal data cannot be obtained. Many different programs were used in each step for the ab initio structure determination, both to test the solution found and to compare different computing methods.
Structure, cation distribution, Mn oxidation states, and conductivity behavior of the Mn-substituted (up to 30% of Ti ions) Li 4 Ti 5 O 12 have been investigated by the combined use of X-ray powder diffraction, electron paramagnetic resonance (EPR), 7 Li MAS NMR, and impedance spectroscopy techniques. The spinel structure of the lithium titanate is preserved and the lattice parameter decreases with increasing the Mn content. Mn 2+ ions progressively occupy the tetrahedral site up to an approximately constant value reached for 10% Mn-substituted samples. Mn 3+ ions occupy both octahedral and tetrahedral sites, with a constant value on the tetrahedral one, independent of the total Mn amount; Mn 4+ ions are not detected. The Mn 2+ paramagnetic ions give rise to a through-space interaction with Li + ions of both cationic sites, as evaluated by the area, proportional to the Mn 2+ ions content, of a peak at ∼8 ppm observed in the 7 Li NMR spectra for the substituted samples. The obtained cation distribution and the Mn valence states satisfactorily explain the decrease of conductivity observed in the Mn-doped samples with respect to the pure Li 4 Ti 5 O 12 .
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