Analysis of temperature-limited flow, space-chargelimited flow, and the transition between them using a simple planar diode with a thermionic cathode, in which the cathode surface has spatially nonuniform emission properties, is presented. Our theoretical results, which are derived from a model based on solutions to the Vlasov and Poisson equations, compare well with the results of particle-in-cell simulations. We find that the location and the shape of the knee in the anode current versus temperature characteristic (Miram or "rollover" curve) are significantly affected by non-uniformities in the space-charge density in the A-K gap, but are relatively unaffected by the electron motion parallel to the electrode surfaces. In particular, emission from an actively emitting region is strongly affected by the forces (or lack thereof) exerted by the space-charge of the electrons emitted by their neighbors. Perhaps, most remarkably, we find that the limiting current reaching the anode is approximately given by the classical 1-D Child-Langmuir law, even if a significant fraction of the cathode surface is nonemitting.

Engineering a material's work function is of central importance for many technologies and in particular electron emitters used in high‐power vacuum electronics and thermionic energy converters. A low work function surface is typically achieved through unstable surface functional species, especially in high power thermionic electron emitter applications. Discovering and engineering new materials with intrinsic, stable low work functions obtainable without volatile surface species would mark a definitive advancement in the design of electron emitters. This work reports evidence for the existence of a low work function surface on a bulk, monolithic, electrically conductive perovskite oxide: SrVO3. After considering the patch field effect on the heterogeneous emitting surface of the bulk polycrystalline samples, this study suggests the presence of low work function (≈2 eV) emissive grains on SrVO3 surface. Emission current densities of 10–100 mA cm–2 at ≈1000 °C, comparable to commercial LaB6 thermionic cathodes, indicative of an overall effective thermionic work function of 2.3–2.7 eV are obtained. This study demonstrates that perovskites like SrVO3 may have intrinsically low work functions comparable to commercialized W‐based dispenser cathodes and suggests that, with further engineering, perovskites may represent a new class of low work function electron emitters.

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